Synthesis and reactivity of bucky ruthenocene Ru(η5-C 60Me5)(η5-C5H5)

Yutaka Matsuo; Yoichiro Kuninobu; Shingo Ito; Eiichi Nakamura

doi:10.1246/cl.2004.68

Synthesis and reactivity of bucky ruthenocene Ru(η⁵-C ₆₀Me₅)(η⁵-C₅H₅)

Yutaka Matsuo, Yoichiro Kuninobu, Shingo Ito, Eiichi Nakamura

Research output: Contribution to journal › Article › peer-review

57 Citations (Scopus)

Abstract

Metathetical coupling of an η⁵-fullerene ruthenium complex Ru(η⁵-C₆₀Me₅)Cl(CO)₂ and sodium cyclopentadienide gives a molecular hybrid of ruthenocene and fullerene, Ru(η⁵-C₆₀Me₅)(η⁵-C ₅H₅) (bucky ruthenocene), the structure of which was determined by spectroscopic and crystallographic analyses. The molecule shows unique reactivity among known ferrocene and ruthenocene compounds.

Original language	English
Pages (from-to)	68-69
Number of pages	2
Journal	Chemistry Letters
Volume	33
Issue number	1
DOIs	https://doi.org/10.1246/cl.2004.68
Publication status	Published - Jan 5 2004
Externally published	Yes

All Science Journal Classification (ASJC) codes

Chemistry(all)

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10.1246/cl.2004.68

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abstract = "Metathetical coupling of an η5-fullerene ruthenium complex Ru(η5-C60Me5)Cl(CO)2 and sodium cyclopentadienide gives a molecular hybrid of ruthenocene and fullerene, Ru(η5-C60Me5)(η5-C 5H5) (bucky ruthenocene), the structure of which was determined by spectroscopic and crystallographic analyses. The molecule shows unique reactivity among known ferrocene and ruthenocene compounds.",

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AU - Ito, Shingo

AU - Nakamura, Eiichi

PY - 2004/1/5

Y1 - 2004/1/5

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AB - Metathetical coupling of an η5-fullerene ruthenium complex Ru(η5-C60Me5)Cl(CO)2 and sodium cyclopentadienide gives a molecular hybrid of ruthenocene and fullerene, Ru(η5-C60Me5)(η5-C 5H5) (bucky ruthenocene), the structure of which was determined by spectroscopic and crystallographic analyses. The molecule shows unique reactivity among known ferrocene and ruthenocene compounds.

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Synthesis and reactivity of bucky ruthenocene Ru(η⁵-C ₆₀Me₅)(η⁵-C₅H₅)

Abstract

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