Synthesis and reactivity of a water-soluble NiRu monohydride complex with a tethered pyridine moiety

Takahiro Matsumoto; Koji Yoshimoto; Chunbai Zheng; Yasuhito Shomura; Yoshiki Higuchi; Hidetaka Nakai; Seiji Ogo

doi:10.1246/cl.151029

Synthesis and reactivity of a water-soluble NiRu monohydride complex with a tethered pyridine moiety

Takahiro Matsumoto, Koji Yoshimoto, Chunbai Zheng, Yasuhito Shomura, Yoshiki Higuchi, Hidetaka Nakai, Seiji Ogo

Research output: Contribution to journal › Article › peer-review

4 Citations (Scopus)

Abstract

We report the synthesis, characterization, and reactivity of a NiRu monohydride complex with a pyridine-bound hexamethylbenzene ligand. We investigate the mechanistic insights it provides on the H₂-activation of [NiFe]hydrogenase.

Original language	English
Pages (from-to)	197-199
Number of pages	3
Journal	Chemistry Letters
Volume	45
Issue number	2
DOIs	https://doi.org/10.1246/cl.151029
Publication status	Published - 2016

All Science Journal Classification (ASJC) codes

Chemistry(all)

Access to Document

10.1246/cl.151029

Cite this

@article{7230446f5c754306a14dcd6b50ba61bf,

title = "Synthesis and reactivity of a water-soluble NiRu monohydride complex with a tethered pyridine moiety",

abstract = "We report the synthesis, characterization, and reactivity of a NiRu monohydride complex with a pyridine-bound hexamethylbenzene ligand. We investigate the mechanistic insights it provides on the H2-activation of [NiFe]hydrogenase.",

author = "Takahiro Matsumoto and Koji Yoshimoto and Chunbai Zheng and Yasuhito Shomura and Yoshiki Higuchi and Hidetaka Nakai and Seiji Ogo",

note = "Publisher Copyright: {\textcopyright} 2016 The Chemical Society of Japan.",

year = "2016",

doi = "10.1246/cl.151029",

language = "English",

volume = "45",

pages = "197--199",

journal = "Chemistry Letters",

issn = "0366-7022",

publisher = "The Chemical Society of Japan",

number = "2",

}

TY - JOUR

T1 - Synthesis and reactivity of a water-soluble NiRu monohydride complex with a tethered pyridine moiety

AU - Matsumoto, Takahiro

AU - Yoshimoto, Koji

AU - Zheng, Chunbai

AU - Shomura, Yasuhito

AU - Higuchi, Yoshiki

AU - Nakai, Hidetaka

AU - Ogo, Seiji

PY - 2016

Y1 - 2016

N2 - We report the synthesis, characterization, and reactivity of a NiRu monohydride complex with a pyridine-bound hexamethylbenzene ligand. We investigate the mechanistic insights it provides on the H2-activation of [NiFe]hydrogenase.

AB - We report the synthesis, characterization, and reactivity of a NiRu monohydride complex with a pyridine-bound hexamethylbenzene ligand. We investigate the mechanistic insights it provides on the H2-activation of [NiFe]hydrogenase.

UR - http://www.scopus.com/inward/record.url?scp=84958953372&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84958953372&partnerID=8YFLogxK

U2 - 10.1246/cl.151029

DO - 10.1246/cl.151029

M3 - Article

AN - SCOPUS:84958953372

SN - 0366-7022

VL - 45

SP - 197

EP - 199

JO - Chemistry Letters

JF - Chemistry Letters

IS - 2

ER -

Synthesis and reactivity of a water-soluble NiRu monohydride complex with a tethered pyridine moiety

Abstract

All Science Journal Classification (ASJC) codes

Access to Document

Other files and links

Fingerprint

Cite this