Synthesis and electronic properties of ferrocene-containing organic dyads

Motonori Watanabe; Yuan Jay Chang; Po Ting Chou; Aleksandar Staykov; Masahiko Shibahara; Katsuya Sako; Tatsumi Ishihara; Tahsin J. Chow

doi:10.1016/j.tetlet.2015.02.012

Synthesis and electronic properties of ferrocene-containing organic dyads

Motonori Watanabe, Yuan Jay Chang, Po Ting Chou, Aleksandar Staykov, Masahiko Shibahara, Katsuya Sako, Tatsumi Ishihara, Tahsin J. Chow

Research output: Contribution to journal › Article › peer-review

6 Citations (Scopus)

Abstract

Novel ferrocene-oligothiophenylene-cyanoacrylic acid in the form of donor-spacer-acceptor dyads was synthesized. The compound with a single unit of thiophenylene showed the lowest energy transition in neutral state. For radical cations, the lowest energy transition appears red-shifted along with the increased number of thiophenylene units. These results suggested that the electronic structure of radical cations is significantly different from that of neutral molecules.

Original language	English
Pages (from-to)	1548-1551
Number of pages	4
Journal	Tetrahedron Letters
Volume	56
Issue number	12
DOIs	https://doi.org/10.1016/j.tetlet.2015.02.012
Publication status	Published - Mar 18 2015

All Science Journal Classification (ASJC) codes

Biochemistry
Drug Discovery
Organic Chemistry

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10.1016/j.tetlet.2015.02.012

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abstract = "Novel ferrocene-oligothiophenylene-cyanoacrylic acid in the form of donor-spacer-acceptor dyads was synthesized. The compound with a single unit of thiophenylene showed the lowest energy transition in neutral state. For radical cations, the lowest energy transition appears red-shifted along with the increased number of thiophenylene units. These results suggested that the electronic structure of radical cations is significantly different from that of neutral molecules.",

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T1 - Synthesis and electronic properties of ferrocene-containing organic dyads

AU - Watanabe, Motonori

AU - Chang, Yuan Jay

AU - Chou, Po Ting

AU - Staykov, Aleksandar

AU - Shibahara, Masahiko

AU - Sako, Katsuya

AU - Ishihara, Tatsumi

AU - Chow, Tahsin J.

PY - 2015/3/18

Y1 - 2015/3/18

N2 - Novel ferrocene-oligothiophenylene-cyanoacrylic acid in the form of donor-spacer-acceptor dyads was synthesized. The compound with a single unit of thiophenylene showed the lowest energy transition in neutral state. For radical cations, the lowest energy transition appears red-shifted along with the increased number of thiophenylene units. These results suggested that the electronic structure of radical cations is significantly different from that of neutral molecules.

AB - Novel ferrocene-oligothiophenylene-cyanoacrylic acid in the form of donor-spacer-acceptor dyads was synthesized. The compound with a single unit of thiophenylene showed the lowest energy transition in neutral state. For radical cations, the lowest energy transition appears red-shifted along with the increased number of thiophenylene units. These results suggested that the electronic structure of radical cations is significantly different from that of neutral molecules.

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VL - 56

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EP - 1551

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 12

ER -

Synthesis and electronic properties of ferrocene-containing organic dyads

Abstract

All Science Journal Classification (ASJC) codes

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