Synthesis and detection of a seaborgium carbonyl complex

J. Even; A. Yakushev; Ch E. Düllmann; H. Haba; M. Asai; T. K. Sato; H. Brand; A. Di Nitto; R. Eichler; F. L. Fan; W. Hartmann; M. Huang; E. Jäger; D. Kaji; J. Kanaya; Y. Kaneya; J. Khuyagbaatar; B. Kindler; J. V. Kratz; J. Krier; Y. Kudou; N. Kurz; B. Lommel; S. Miyashita; K. Morimoto; K. Morita; M. Murakami; Y. Nagame; H. Nitsche; K. Ooe; Z. Qin; M. Schädel; J. Steiner; T. Sumita; M. Takeyama; K. Tanaka; A. Toyoshima; K. Tsukada; A. Türler; I. Usoltsev; Y. Wakabayashi; Y. Wang; N. Wiehl; S. Yamaki

doi:10.1126/science.1255720

Synthesis and detection of a seaborgium carbonyl complex

J. Even, A. Yakushev, Ch E. Düllmann, H. Haba, M. Asai, T. K. Sato, H. Brand, A. Di Nitto, R. Eichler, F. L. Fan, W. Hartmann, M. Huang, E. Jäger, D. Kaji, J. Kanaya, Y. Kaneya, J. Khuyagbaatar, B. Kindler, J. V. Kratz, J. KrierY. Kudou, N. Kurz, B. Lommel, S. Miyashita, K. Morimoto, K. Morita, M. Murakami, Y. Nagame, H. Nitsche, K. Ooe, Z. Qin, M. Schädel, J. Steiner, T. Sumita, M. Takeyama, K. Tanaka, A. Toyoshima, K. Tsukada, A. Türler, I. Usoltsev, Y. Wakabayashi, Y. Wang, N. Wiehl, S. Yamaki

Experimental Particle Physics

Research output: Contribution to journal › Article › peer-review

68 Citations (Scopus)

Abstract

Experimental investigations of transactinoide elements provide benchmark results for chemical theory and probe the predictive power of trends in the periodic table. So far, in gas-phase chemical reactions, simple inorganic compounds with the transactinoide in its highest oxidation state have been synthesized. Single-atom production rates, short half-lives, and harsh experimental conditions limited the number of experimentally accessible compounds. We applied a gas-phase carbonylation technique previously tested on short-lived molybdenum (Mo) and tungsten (W) isotopes to the preparation of a carbonyl complex of seaborgium, the 106th element. The volatile seaborgium complex showed the same volatility and reactivity with a silicon dioxide surface as those of the hexacarbonyl complexes of the lighter homologs Mo and W. Comparison of the product's adsorption enthalpy with theoretical predictions and data for the lighter congeners supported a Sg(CO)⁶formulation.

Original language	English
Pages (from-to)	1491-1493
Number of pages	3
Journal	Science
Volume	345
Issue number	6203
DOIs	https://doi.org/10.1126/science.1255720
Publication status	Published - Sept 19 2014

All Science Journal Classification (ASJC) codes

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10.1126/science.1255720

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Even, J., Yakushev, A., Düllmann, C. E., Haba, H., Asai, M., Sato, T. K., Brand, H., Di Nitto, A., Eichler, R., Fan, F. L., Hartmann, W., Huang, M., Jäger, E., Kaji, D., Kanaya, J., Kaneya, Y., Khuyagbaatar, J., Kindler, B., Kratz, J. V., ... Yamaki, S. (2014). Synthesis and detection of a seaborgium carbonyl complex. Science, 345(6203), 1491-1493. https://doi.org/10.1126/science.1255720

Even, J, Yakushev, A, Düllmann, CE, Haba, H, Asai, M, Sato, TK, Brand, H, Di Nitto, A, Eichler, R, Fan, FL, Hartmann, W, Huang, M, Jäger, E, Kaji, D, Kanaya, J, Kaneya, Y, Khuyagbaatar, J, Kindler, B, Kratz, JV, Krier, J, Kudou, Y, Kurz, N, Lommel, B, Miyashita, S, Morimoto, K, Morita, K, Murakami, M, Nagame, Y, Nitsche, H, Ooe, K, Qin, Z, Schädel, M, Steiner, J, Sumita, T, Takeyama, M, Tanaka, K, Toyoshima, A, Tsukada, K, Türler, A, Usoltsev, I, Wakabayashi, Y, Wang, Y, Wiehl, N & Yamaki, S 2014, 'Synthesis and detection of a seaborgium carbonyl complex', Science, vol. 345, no. 6203, pp. 1491-1493. https://doi.org/10.1126/science.1255720

@article{9d51ead339bb470bb9f32e0a2f223ed4,

title = "Synthesis and detection of a seaborgium carbonyl complex",

abstract = "Experimental investigations of transactinoide elements provide benchmark results for chemical theory and probe the predictive power of trends in the periodic table. So far, in gas-phase chemical reactions, simple inorganic compounds with the transactinoide in its highest oxidation state have been synthesized. Single-atom production rates, short half-lives, and harsh experimental conditions limited the number of experimentally accessible compounds. We applied a gas-phase carbonylation technique previously tested on short-lived molybdenum (Mo) and tungsten (W) isotopes to the preparation of a carbonyl complex of seaborgium, the 106th element. The volatile seaborgium complex showed the same volatility and reactivity with a silicon dioxide surface as those of the hexacarbonyl complexes of the lighter homologs Mo and W. Comparison of the product's adsorption enthalpy with theoretical predictions and data for the lighter congeners supported a Sg(CO)6formulation.",

author = "J. Even and A. Yakushev and D{\"u}llmann, {Ch E.} and H. Haba and M. Asai and Sato, {T. K.} and H. Brand and {Di Nitto}, A. and R. Eichler and Fan, {F. L.} and W. Hartmann and M. Huang and E. J{\"a}ger and D. Kaji and J. Kanaya and Y. Kaneya and J. Khuyagbaatar and B. Kindler and Kratz, {J. V.} and J. Krier and Y. Kudou and N. Kurz and B. Lommel and S. Miyashita and K. Morimoto and K. Morita and M. Murakami and Y. Nagame and H. Nitsche and K. Ooe and Z. Qin and M. Sch{\"a}del and J. Steiner and T. Sumita and M. Takeyama and K. Tanaka and A. Toyoshima and K. Tsukada and A. T{\"u}rler and I. Usoltsev and Y. Wakabayashi and Y. Wang and N. Wiehl and S. Yamaki",

year = "2014",

month = sep,

day = "19",

doi = "10.1126/science.1255720",

language = "English",

volume = "345",

pages = "1491--1493",

journal = "Science",

issn = "0036-8075",

publisher = "American Association for the Advancement of Science",

number = "6203",

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TY - JOUR

T1 - Synthesis and detection of a seaborgium carbonyl complex

AU - Even, J.

AU - Yakushev, A.

AU - Düllmann, Ch E.

AU - Haba, H.

AU - Asai, M.

AU - Sato, T. K.

AU - Brand, H.

AU - Di Nitto, A.

AU - Eichler, R.

AU - Fan, F. L.

AU - Hartmann, W.

AU - Huang, M.

AU - Jäger, E.

AU - Kaji, D.

AU - Kanaya, J.

AU - Kaneya, Y.

AU - Khuyagbaatar, J.

AU - Kindler, B.

AU - Kratz, J. V.

AU - Krier, J.

AU - Kudou, Y.

AU - Kurz, N.

AU - Lommel, B.

AU - Miyashita, S.

AU - Morimoto, K.

AU - Morita, K.

AU - Murakami, M.

AU - Nagame, Y.

AU - Nitsche, H.

AU - Ooe, K.

AU - Qin, Z.

AU - Schädel, M.

AU - Steiner, J.

AU - Sumita, T.

AU - Takeyama, M.

AU - Tanaka, K.

AU - Toyoshima, A.

AU - Tsukada, K.

AU - Türler, A.

AU - Usoltsev, I.

AU - Wakabayashi, Y.

AU - Wang, Y.

AU - Wiehl, N.

AU - Yamaki, S.

PY - 2014/9/19

Y1 - 2014/9/19

N2 - Experimental investigations of transactinoide elements provide benchmark results for chemical theory and probe the predictive power of trends in the periodic table. So far, in gas-phase chemical reactions, simple inorganic compounds with the transactinoide in its highest oxidation state have been synthesized. Single-atom production rates, short half-lives, and harsh experimental conditions limited the number of experimentally accessible compounds. We applied a gas-phase carbonylation technique previously tested on short-lived molybdenum (Mo) and tungsten (W) isotopes to the preparation of a carbonyl complex of seaborgium, the 106th element. The volatile seaborgium complex showed the same volatility and reactivity with a silicon dioxide surface as those of the hexacarbonyl complexes of the lighter homologs Mo and W. Comparison of the product's adsorption enthalpy with theoretical predictions and data for the lighter congeners supported a Sg(CO)6formulation.

AB - Experimental investigations of transactinoide elements provide benchmark results for chemical theory and probe the predictive power of trends in the periodic table. So far, in gas-phase chemical reactions, simple inorganic compounds with the transactinoide in its highest oxidation state have been synthesized. Single-atom production rates, short half-lives, and harsh experimental conditions limited the number of experimentally accessible compounds. We applied a gas-phase carbonylation technique previously tested on short-lived molybdenum (Mo) and tungsten (W) isotopes to the preparation of a carbonyl complex of seaborgium, the 106th element. The volatile seaborgium complex showed the same volatility and reactivity with a silicon dioxide surface as those of the hexacarbonyl complexes of the lighter homologs Mo and W. Comparison of the product's adsorption enthalpy with theoretical predictions and data for the lighter congeners supported a Sg(CO)6formulation.

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DO - 10.1126/science.1255720

M3 - Article

AN - SCOPUS:84907211064

SN - 0036-8075

VL - 345

SP - 1491

EP - 1493

JO - Science

JF - Science

IS - 6203

ER -

Synthesis and detection of a seaborgium carbonyl complex

Abstract

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