Synthesis and characterization of a tetrahedral and octahedral cobalt(II) alternate chain complex

Hitoshi Kumagai; Masaaki Ohba; Katsuya Inoue; Hisashi Okawa

doi:10.1246/cl.2002.1006

Synthesis and characterization of a tetrahedral and octahedral cobalt(II) alternate chain complex

Hitoshi Kumagai, Masaaki Ohba, Katsuya Inoue, Hisashi Okawa

Inorganic and Analytical Chemistry

Research output: Contribution to journal › Article › peer-review

7 Citations (Scopus)

Abstract

Reaction between Co(II) ion and 4-phenoxybenzoate (L) under hydrothermal conditions gives a one-dimensional coordination polymer, [Co₂L₄]. [Co₂L₄] consists of dinuclear motifs of pseudo octahedral {CoO₆} and tetrahedral {CoO₄} linked through μ-carboxylate ligands. The temperature dependence of magnetic susceptibility revealed the presence of ferromagnetic interaction between the adjacent tetrahedral Co(II) and octahedral Co(II) ions.

Original language	English
Pages (from-to)	1006-1007
Number of pages	2
Journal	Chemistry Letters
Issue number	10
DOIs	https://doi.org/10.1246/cl.2002.1006
Publication status	Published - Oct 5 2002

All Science Journal Classification (ASJC) codes

Chemistry(all)

Access to Document

10.1246/cl.2002.1006

Cite this

@article{7b77cb5ea8e14b088438e6c67aced245,

title = "Synthesis and characterization of a tetrahedral and octahedral cobalt(II) alternate chain complex",

abstract = "Reaction between Co(II) ion and 4-phenoxybenzoate (L) under hydrothermal conditions gives a one-dimensional coordination polymer, [Co2L4]. [Co2L4] consists of dinuclear motifs of pseudo octahedral {CoO6} and tetrahedral {CoO4} linked through μ-carboxylate ligands. The temperature dependence of magnetic susceptibility revealed the presence of ferromagnetic interaction between the adjacent tetrahedral Co(II) and octahedral Co(II) ions.",

author = "Hitoshi Kumagai and Masaaki Ohba and Katsuya Inoue and Hisashi Okawa",

year = "2002",

month = oct,

day = "5",

doi = "10.1246/cl.2002.1006",

language = "English",

pages = "1006--1007",

journal = "Chemistry Letters",

issn = "0366-7022",

publisher = "The Chemical Society of Japan",

number = "10",

}

TY - JOUR

T1 - Synthesis and characterization of a tetrahedral and octahedral cobalt(II) alternate chain complex

AU - Kumagai, Hitoshi

AU - Ohba, Masaaki

AU - Inoue, Katsuya

AU - Okawa, Hisashi

PY - 2002/10/5

Y1 - 2002/10/5

N2 - Reaction between Co(II) ion and 4-phenoxybenzoate (L) under hydrothermal conditions gives a one-dimensional coordination polymer, [Co2L4]. [Co2L4] consists of dinuclear motifs of pseudo octahedral {CoO6} and tetrahedral {CoO4} linked through μ-carboxylate ligands. The temperature dependence of magnetic susceptibility revealed the presence of ferromagnetic interaction between the adjacent tetrahedral Co(II) and octahedral Co(II) ions.

AB - Reaction between Co(II) ion and 4-phenoxybenzoate (L) under hydrothermal conditions gives a one-dimensional coordination polymer, [Co2L4]. [Co2L4] consists of dinuclear motifs of pseudo octahedral {CoO6} and tetrahedral {CoO4} linked through μ-carboxylate ligands. The temperature dependence of magnetic susceptibility revealed the presence of ferromagnetic interaction between the adjacent tetrahedral Co(II) and octahedral Co(II) ions.

UR - http://www.scopus.com/inward/record.url?scp=0037027239&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0037027239&partnerID=8YFLogxK

U2 - 10.1246/cl.2002.1006

DO - 10.1246/cl.2002.1006

M3 - Article

AN - SCOPUS:0037027239

SN - 0366-7022

SP - 1006

EP - 1007

JO - Chemistry Letters

JF - Chemistry Letters

IS - 10

ER -

Synthesis and characterization of a tetrahedral and octahedral cobalt(II) alternate chain complex

Abstract

All Science Journal Classification (ASJC) codes

Access to Document

Other files and links

Fingerprint

Cite this