Surface segregation of poly(2-methoxyethyl acrylate) in a mixture with poly(methyl methacrylate)

Toyoaki Hirata, Hisao Matsuno, Masaru Tanaka, Keiji Tanaka

    Research output: Contribution to journalArticlepeer-review

    30 Citations (Scopus)


    Poly(2-methoxyethyl acrylate) (PMEA) exhibits excellent blood compatibility. To understand why such a surface functionality exists, the surface of PMEA should be characterized in detail, structurally and dynamically, under not only ambient conditions, but also in water. However, a thin film of PMEA supported on a solid substrate can be easily broken, namely it is dewetted. Our strategy to overcome this difficulty is to mix PMEA with poly(methyl methacrylate) (PMMA). Differential scanning calorimetry and cloud point measurements revealed that the PMEA/PMMA blend has a phase diagram with a lower critical solution temperature. The blend surface was also characterized by X-ray photoelectron spectroscopy in conjunction with microscopic observations. Although PMEA is preferentially segregated over PMMA at the blend surface due to its lower surface free energy, the extent of segregation in the as-prepared films was not sufficient to cover the surface. Annealing the blend film at an appropriate temperature, higher than the glass transition temperature and lower than the phase-separation temperature of the blend, enabled us to prepare a stable and flat surface that was perfectly covered with PMEA.

    Original languageEnglish
    Pages (from-to)4928-4934
    Number of pages7
    JournalPhysical Chemistry Chemical Physics
    Issue number11
    Publication statusPublished - Mar 21 2011

    All Science Journal Classification (ASJC) codes

    • General Physics and Astronomy
    • Physical and Theoretical Chemistry


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