Supramolecular architectures self-assembled using long chain alkylated spin crossover cobalt(II) compounds

Ryohei Akiyoshi; Keita Kuroiwa; Saliu Alao Amolegbe; Manabu Nakaya; Ryo Ohtani; Masaaki Nakamura; Leonard F. Lindoy; Shinya Hayami

doi:10.1039/c7cc01501a

Supramolecular architectures self-assembled using long chain alkylated spin crossover cobalt(II) compounds

Ryohei Akiyoshi, Keita Kuroiwa, Saliu Alao Amolegbe, Manabu Nakaya, Ryo Ohtani, Masaaki Nakamura, Leonard F. Lindoy, Shinya Hayami

Research output: Contribution to journal › Article › peer-review

11 Citations (Scopus)

Abstract

Self-assembled hybrid supramolecular architectures formed between amphiphilic anions and long alkylated cationic cobalt(ii) complexes of type [Co(C_n-terpy)₂](C₁₂-Glu)₂ (n = 15-20) have been synthesized and characterized by TEM, PXRD and magnetic susceptibility measurements. The hybrids display wire or rolled sheet supramolecular arrangements with odd and even alkyl chain dependence, with the cobalt(ii) centres exhibiting gradual spin-crossover behaviours.

Original language	English
Pages (from-to)	4685-4687
Number of pages	3
Journal	Chemical Communications
Volume	53
Issue number	34
DOIs	https://doi.org/10.1039/c7cc01501a
Publication status	Published - 2017
Externally published	Yes

All Science Journal Classification (ASJC) codes

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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10.1039/c7cc01501a

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title = "Supramolecular architectures self-assembled using long chain alkylated spin crossover cobalt(II) compounds",

abstract = "Self-assembled hybrid supramolecular architectures formed between amphiphilic anions and long alkylated cationic cobalt(ii) complexes of type [Co(Cn-terpy)2](C12-Glu)2 (n = 15-20) have been synthesized and characterized by TEM, PXRD and magnetic susceptibility measurements. The hybrids display wire or rolled sheet supramolecular arrangements with odd and even alkyl chain dependence, with the cobalt(ii) centres exhibiting gradual spin-crossover behaviours.",

author = "Ryohei Akiyoshi and Keita Kuroiwa and {Alao Amolegbe}, Saliu and Manabu Nakaya and Ryo Ohtani and Masaaki Nakamura and Lindoy, {Leonard F.} and Shinya Hayami",

note = "Publisher Copyright: {\textcopyright} 2017 The Royal Society of Chemistry.",

year = "2017",

doi = "10.1039/c7cc01501a",

language = "English",

volume = "53",

pages = "4685--4687",

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publisher = "Royal Society of Chemistry",

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T1 - Supramolecular architectures self-assembled using long chain alkylated spin crossover cobalt(II) compounds

AU - Akiyoshi, Ryohei

AU - Kuroiwa, Keita

AU - Alao Amolegbe, Saliu

AU - Nakaya, Manabu

AU - Ohtani, Ryo

AU - Nakamura, Masaaki

AU - Lindoy, Leonard F.

AU - Hayami, Shinya

PY - 2017

Y1 - 2017

N2 - Self-assembled hybrid supramolecular architectures formed between amphiphilic anions and long alkylated cationic cobalt(ii) complexes of type [Co(Cn-terpy)2](C12-Glu)2 (n = 15-20) have been synthesized and characterized by TEM, PXRD and magnetic susceptibility measurements. The hybrids display wire or rolled sheet supramolecular arrangements with odd and even alkyl chain dependence, with the cobalt(ii) centres exhibiting gradual spin-crossover behaviours.

AB - Self-assembled hybrid supramolecular architectures formed between amphiphilic anions and long alkylated cationic cobalt(ii) complexes of type [Co(Cn-terpy)2](C12-Glu)2 (n = 15-20) have been synthesized and characterized by TEM, PXRD and magnetic susceptibility measurements. The hybrids display wire or rolled sheet supramolecular arrangements with odd and even alkyl chain dependence, with the cobalt(ii) centres exhibiting gradual spin-crossover behaviours.

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AN - SCOPUS:85021685189

SN - 1359-7345

VL - 53

SP - 4685

EP - 4687

JO - Chemical Communications

JF - Chemical Communications

IS - 34

ER -

Supramolecular architectures self-assembled using long chain alkylated spin crossover cobalt(II) compounds

Abstract

All Science Journal Classification (ASJC) codes

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