Superprotonic conductivity in a highly oriented crystalline metal-organic framework nanofilm

Gang Xu; Kazuya Otsubo; Teppei Yamada; Shun Sakaida; Hiroshi Kitagawa

doi:10.1021/ja402727d

Superprotonic conductivity in a highly oriented crystalline metal-organic framework nanofilm

Gang Xu, Kazuya Otsubo, Teppei Yamada, Shun Sakaida, Hiroshi Kitagawa

Applied Chemistry

Research output: Contribution to journal › Article › peer-review

287 Citations (Scopus)

Abstract

The electrical properties of a highly oriented crystalline MOF nanofilm were studied. This nanofilm has low activation energy and a proton conductivity that is among the highest value reported for MOF materials. The study uncovered the reasons for the excellent performance of this nanofilm and revealed a new pathway for proton transport in MOF materials; besides the channels inside a MOF, the surface of the MOF nanocrystal can also dominate proton transport.

Original language	English
Pages (from-to)	7438-7441
Number of pages	4
Journal	Journal of the American Chemical Society
Volume	135
Issue number	20
DOIs	https://doi.org/10.1021/ja402727d
Publication status	Published - May 22 2013

All Science Journal Classification (ASJC) codes

Catalysis
Chemistry(all)
Biochemistry
Colloid and Surface Chemistry

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10.1021/ja402727d

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abstract = "The electrical properties of a highly oriented crystalline MOF nanofilm were studied. This nanofilm has low activation energy and a proton conductivity that is among the highest value reported for MOF materials. The study uncovered the reasons for the excellent performance of this nanofilm and revealed a new pathway for proton transport in MOF materials; besides the channels inside a MOF, the surface of the MOF nanocrystal can also dominate proton transport.",

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AU - Xu, Gang

AU - Otsubo, Kazuya

AU - Yamada, Teppei

AU - Sakaida, Shun

AU - Kitagawa, Hiroshi

PY - 2013/5/22

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Superprotonic conductivity in a highly oriented crystalline metal-organic framework nanofilm

Abstract

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