Study on mass discrimination effect of resonance ionization mass spectrometry using an inductively coupled plasma as an atomic source (ICP-RIMS)

Y. Higuchi, K. Watanabe, H. Tomita, J. Kawarabayashi, T. Iguchi

Research output: Contribution to journalConference articlepeer-review

Abstract

We have proposed a novel concept of Resonance Ionization Mass Spectrometry using an Inductively Coupled Plasma as an Atomic Source (ICP-RIMS). Isotope ratio analysis using ICP-RIMS is expected to be a convenient and precise technique with high throughput. However, the mass discrimination effect caused from difference in kinetic energy of neutral atoms in ICP- RIMS is crucial for precise isotope analysis. We, therefore, investigated the atom kinetic energy distribution introduced into the laser ionization region. The mass-dependent kinetic energy was confirmed in the initial kinetic energy distributions. We preliminary estimated a mass discrimination effect caused by mass-dependent kinetic energy in ICP-RIMS for various detector sizes. We proposed that this effect can be suppressed by selecting the appropriate detector size and adopting the scanning mode of the deflecting voltage.

Original languageEnglish
Pages (from-to)179-184
Number of pages6
JournalAIP Conference Proceedings
Volume1104
DOIs
Publication statusPublished - 2009
Externally publishedYes
Event4th International Conference on Laser Probing, LAP 2008 - Nagoya, Japan
Duration: Oct 6 2009Oct 10 2009

All Science Journal Classification (ASJC) codes

  • Physics and Astronomy(all)

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