TY - JOUR
T1 - Structure and magnetic property of µ-oxo bridged dinuclear iron(III) complex with trialkylated tridentated ligands
AU - Tsutsumi, Mayu
AU - Kobayashi, Fumiya
AU - Ohtani, Ryo
AU - Nakamura, Msaaki
AU - Hayami, Shinya
N1 - Funding Information:
This work was supported by the KAKENHI Grant-in-Aid for Scientific Research (A) JP17H01200. This work was also supported by the JSPS Grant-in-Aid for Young Scientists (B) JP15K17833 and the JSPS Grant-in-Aid for Scientific Research on Innovative Areas (Dynamical Ordering & Integrated Functions JP16H00777, Mixed Anion JP17H05485). This work was partially supported by the Cooperative Research Program of ‘Network Joint Research Centre for Materials and Devices’.
Publisher Copyright:
© 2018, Springer Science+Business Media B.V., part of Springer Nature.
PY - 2019/8/15
Y1 - 2019/8/15
N2 - µ-Oxo bridged dinuclear iron(III) complex with trialkylated tridentate ligand [Fe2(µ-O)(3C8-bzimpy)2Cl4]·CHCl3 (1, and 3C8-bzimpy = 2,6-bis(N-octylbenzimidazol-2′-yl)-4-octyloxypyridine) was synthesized and the magnetic property was investigated. Single crystal X-ray structural analysis of complex 1 revealed µ-oxo bridged dinuclear structure with N3OCl2 donor set. Complex 1 has constructed one-dimensional chain structure by CH–π interactions and CH–Cl hydrogen bonds, and further formed a two-dimensional layer parallel to the ab plane by fastener effect of trialkylated ligands. Magnetic susceptibility measurement of 1 showed the antiferromagnetic interactions through µ-oxo bridge, and the best fits for their behavior gave the following parameters: J = −12.7 cm− 1, g = 2.
AB - µ-Oxo bridged dinuclear iron(III) complex with trialkylated tridentate ligand [Fe2(µ-O)(3C8-bzimpy)2Cl4]·CHCl3 (1, and 3C8-bzimpy = 2,6-bis(N-octylbenzimidazol-2′-yl)-4-octyloxypyridine) was synthesized and the magnetic property was investigated. Single crystal X-ray structural analysis of complex 1 revealed µ-oxo bridged dinuclear structure with N3OCl2 donor set. Complex 1 has constructed one-dimensional chain structure by CH–π interactions and CH–Cl hydrogen bonds, and further formed a two-dimensional layer parallel to the ab plane by fastener effect of trialkylated ligands. Magnetic susceptibility measurement of 1 showed the antiferromagnetic interactions through µ-oxo bridge, and the best fits for their behavior gave the following parameters: J = −12.7 cm− 1, g = 2.
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U2 - 10.1007/s10847-018-0810-4
DO - 10.1007/s10847-018-0810-4
M3 - Article
AN - SCOPUS:85068747053
SN - 0923-0750
VL - 94
SP - 183
EP - 188
JO - Journal of Inclusion Phenomena and Macrocyclic Chemistry
JF - Journal of Inclusion Phenomena and Macrocyclic Chemistry
IS - 3-4
ER -