Strain Effects on Oxygen Reduction Activity of Pr₂NiO₄ Caused by Gold Bulk Dispersion for Low Temperature Solid Oxide Fuel Cells

Effects of tensile strain induced by the dispersion of Au nanoparticles in Pr₂NiO₄-based oxide on the oxygen reduction reaction were investigated. Au-dispersed Pr_1.9Ni_0.71Cu_0.41Ga_0.05O₄₊ (PNCG) showed a much decreased cathodic overpotential, and a cell using Au-dispersed PNCG showed a significantly higher power density, approximately 2.5 times higher than that of a cell using PNCG without dispersed Au. The smallest overpotential was achieved at 3-5 mol % dispersion of Au nanoparticles, at which the largest tensile strain was observed. Impedance measurements suggested that the impedance arc in the lower frequency range was mainly decreased; therefore, the increased activity to oxygen reduction was attributed to the increased bulk and surface diffusivity of oxide ions. Electron energy loss spectroscopy (EELS) shows that oxygen in the strained region was in a more reduced state and this oxygen could be assigned to interstitial oxygen which is highly mobile. In addition, density functional theory (DFT) analysis suggested that bond destabilization was attributed to the increase in energy of occupied ∗ orbitals of surface peroxo species on tensile strained surfaces. Therefore, increased cathodic performance of PNCG by Au nanoparticle dispersion could be assigned to the increased diffusivity by tensile strain.