TY - JOUR
T1 - Stimuli-responsive folding and unfolding of a polymer bearing multiple cerium(IV) bis(porphyrinate) joints
T2 - Mechano-imitation of the action of a folding ruler
AU - Shibata, Masayuki
AU - Tanaka, Satoshi
AU - Ikeda, Tomohiro
AU - Shinkai, Seiji
AU - Kaneko, Kenji
AU - Ogi, Soichiro
AU - Takeuchi, Masayuki
PY - 2013/1/2
Y1 - 2013/1/2
N2 - A pivotal guest role: A new porphyrin polymer, poly(PorZn·DD) (see picture, pink/purple), composed of a porphyrinatozinc and a porphyrin double-decker complex as a repeating unit was synthesized. In poly(PorZn·DD), porphyrinatozinc complexes recognize a divalent amine (tan/red) to induce an intramolecular pivoting motion through the rotation of porphyrin double-decker complexes and the polymer undergoes shortening and compaction.
AB - A pivotal guest role: A new porphyrin polymer, poly(PorZn·DD) (see picture, pink/purple), composed of a porphyrinatozinc and a porphyrin double-decker complex as a repeating unit was synthesized. In poly(PorZn·DD), porphyrinatozinc complexes recognize a divalent amine (tan/red) to induce an intramolecular pivoting motion through the rotation of porphyrin double-decker complexes and the polymer undergoes shortening and compaction.
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U2 - 10.1002/anie.201205584
DO - 10.1002/anie.201205584
M3 - Article
C2 - 23161788
AN - SCOPUS:84871950932
SN - 1433-7851
VL - 52
SP - 397
EP - 400
JO - Angewandte Chemie - International Edition
JF - Angewandte Chemie - International Edition
IS - 1
ER -