TY - JOUR
T1 - Stable Hydrogen Energy Carrier That Stores One Electron in a Cobalt(I) Complex for More Than 3 Months
AU - Ogo, Seiji
AU - Kamitakahara, Kazuki
AU - Yatabe, Takeshi
AU - Hashimoto, Yunosuke
AU - Kanda, Naoto
AU - Nakai, Hidetaka
N1 - Publisher Copyright:
© 2024 American Chemical Society.
PY - 2024
Y1 - 2024
N2 - This paper details a next-generation Co(I)-based hydrogen energy carrier (H2EC) that can readily extract one electron from hydrogen, store the electron for more than 3 months, and use the electron elsewhere when needed. It is noteworthy that the ability of the Co(I) complex to perform reductive coupling is much higher than that of a similar Ni(I) complex that we recently reported. Three X-ray structures are presented: the Co(II) complex before reaction with H2, the Co(I) complex after reaction with H2 (i.e., the H2EC), and a Co(III) chloromethyl complex formed by oxidative addition of dichloromethane to the Co(I) complex.
AB - This paper details a next-generation Co(I)-based hydrogen energy carrier (H2EC) that can readily extract one electron from hydrogen, store the electron for more than 3 months, and use the electron elsewhere when needed. It is noteworthy that the ability of the Co(I) complex to perform reductive coupling is much higher than that of a similar Ni(I) complex that we recently reported. Three X-ray structures are presented: the Co(II) complex before reaction with H2, the Co(I) complex after reaction with H2 (i.e., the H2EC), and a Co(III) chloromethyl complex formed by oxidative addition of dichloromethane to the Co(I) complex.
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U2 - 10.1021/acs.organomet.4c00103
DO - 10.1021/acs.organomet.4c00103
M3 - Article
AN - SCOPUS:85189874976
SN - 0276-7333
JO - Organometallics
JF - Organometallics
ER -