Spin crossover characteristics of nanofibrous FeII-1,2,4- triazole complexes in liquid crystals

Keita Kuroiwa; Hirotsugu Kikuchi; Nobuo Kimizuka

doi:10.1039/b920631k

Spin crossover characteristics of nanofibrous Fe^II-1,2,4- triazole complexes in liquid crystals

Keita Kuroiwa, Hirotsugu Kikuchi, Nobuo Kimizuka

Department of Integrated Materials

Research output: Contribution to journal › Article › peer-review

39 Citations (Scopus)

Abstract

A lipophilic linear Fe^II complex is dispersed as nanofibers in nematic liquid crystals and displays spin-crossover at temperatures higher than those observed for the bulk crystalline state; thermal bistability is also induced in the liquid crystal environment, reflecting increased ligand field splitting energy and enhanced cooperativity by liquid crystals.

Original language	English
Pages (from-to)	1229-1231
Number of pages	3
Journal	Chemical Communications
Volume	46
Issue number	8
DOIs	https://doi.org/10.1039/b920631k
Publication status	Published - 2010

All Science Journal Classification (ASJC) codes

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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title = "Spin crossover characteristics of nanofibrous FeII-1,2,4- triazole complexes in liquid crystals",

abstract = "A lipophilic linear FeII complex is dispersed as nanofibers in nematic liquid crystals and displays spin-crossover at temperatures higher than those observed for the bulk crystalline state; thermal bistability is also induced in the liquid crystal environment, reflecting increased ligand field splitting energy and enhanced cooperativity by liquid crystals.",

author = "Keita Kuroiwa and Hirotsugu Kikuchi and Nobuo Kimizuka",

year = "2010",

doi = "10.1039/b920631k",

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AU - Kuroiwa, Keita

AU - Kikuchi, Hirotsugu

AU - Kimizuka, Nobuo

PY - 2010

Y1 - 2010

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AB - A lipophilic linear FeII complex is dispersed as nanofibers in nematic liquid crystals and displays spin-crossover at temperatures higher than those observed for the bulk crystalline state; thermal bistability is also induced in the liquid crystal environment, reflecting increased ligand field splitting energy and enhanced cooperativity by liquid crystals.

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JO - Chemical Communications

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Spin crossover characteristics of nanofibrous Fe^II-1,2,4- triazole complexes in liquid crystals

Abstract

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