TY - JOUR
T1 - Small molecular hole-transporting and emitting materials for hole-only green organic light-emitting devices
AU - Liu, Xicheng
AU - Liang, Junfei
AU - You, Jing
AU - Ying, Lei
AU - Xiao, Yin
AU - Wang, Shirong
AU - Li, Xianggao
N1 - Funding Information:
The authors gratefully acknowledge the financial support from National High-tech R&D Program (863 Program) ( 2015AA033402 ) and Tianjin science and technology plan projects ( 13ZCZDGX00900 ). The calculation in this work was supported by high performance computing center of Tianjin University , China.
Publisher Copyright:
© 2016 Published by Elsevier Ltd.
PY - 2016/8
Y1 - 2016/8
N2 - Three small molecular hole-transporting and emitting materials with naphthalene bridged triphenylamine or carbazole were synthesized. These compounds exhibited high absolute fluorescence quantum yields (70-88%) at the green light region (540-555 nm), suitable highest occupied molecular orbital levels (-5.26 ∼ -5.34 eV) and good hole mobilities (∼10-4 cm2 V-1 s-1). The hole-only organic light emitting diodes with as-synthesized hole-transporting and emitting materials showed a tune-on voltage and a maximum brightness of 2.6 V and 2010 cd m-2, respectively. Three stages of voltage-dependent current were observed, which coincide with the characteristic of Ohmic current, Fowler-Nordheim current and space charge limited current. With analysis of above models, overlarge Fowler-Nordheim current and space charge limited current contribute to the low efficiency of the device. All these results indicated that the high hole mobility showed the negative effect on the device efficiency, especially at high operation voltage.
AB - Three small molecular hole-transporting and emitting materials with naphthalene bridged triphenylamine or carbazole were synthesized. These compounds exhibited high absolute fluorescence quantum yields (70-88%) at the green light region (540-555 nm), suitable highest occupied molecular orbital levels (-5.26 ∼ -5.34 eV) and good hole mobilities (∼10-4 cm2 V-1 s-1). The hole-only organic light emitting diodes with as-synthesized hole-transporting and emitting materials showed a tune-on voltage and a maximum brightness of 2.6 V and 2010 cd m-2, respectively. Three stages of voltage-dependent current were observed, which coincide with the characteristic of Ohmic current, Fowler-Nordheim current and space charge limited current. With analysis of above models, overlarge Fowler-Nordheim current and space charge limited current contribute to the low efficiency of the device. All these results indicated that the high hole mobility showed the negative effect on the device efficiency, especially at high operation voltage.
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U2 - 10.1016/j.dyepig.2016.03.052
DO - 10.1016/j.dyepig.2016.03.052
M3 - Article
AN - SCOPUS:84964048211
SN - 0143-7208
VL - 131
SP - 41
EP - 48
JO - Dyes and Pigments
JF - Dyes and Pigments
ER -