Slow magnetic relaxation in a 4,2-ribbon like FeIII 2CoII heterobimetallic chain

Soonchul Kang; Shinji Kanegawa; Osamu Sato

doi:10.1039/c2dt31168b

Slow magnetic relaxation in a 4,2-ribbon like Fe^III ₂Co^II heterobimetallic chain

Soonchul Kang, Shinji Kanegawa, Osamu Sato

Department of Fundamental Organic Chemistry

Research output: Contribution to journal › Article › peer-review

5 Citations (Scopus)

Abstract

The reaction of Co(NO₃)₂·6H₂O and 3-benzoylpyridine with the low-spin iron(iii) complex, H[Fe^III(phen) (CN)₄], in methanol gives rise to a cyanide-bridged heterobimetallic chain [{Fe^III(phen)(CN)₄}₂Co ^II(3-bpe)₂] (1) that exhibits intrachain ferromagnetic coupling and slow double magnetic relaxation.

Original language	English
Pages (from-to)	13575-13577
Number of pages	3
Journal	Dalton Transactions
Volume	41
Issue number	44
DOIs	https://doi.org/10.1039/c2dt31168b
Publication status	Published - Nov 28 2012

All Science Journal Classification (ASJC) codes

Inorganic Chemistry

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title = "Slow magnetic relaxation in a 4,2-ribbon like FeIII 2CoII heterobimetallic chain",

abstract = "The reaction of Co(NO3)2·6H2O and 3-benzoylpyridine with the low-spin iron(iii) complex, H[FeIII(phen) (CN)4], in methanol gives rise to a cyanide-bridged heterobimetallic chain [{FeIII(phen)(CN)4}2Co II(3-bpe)2] (1) that exhibits intrachain ferromagnetic coupling and slow double magnetic relaxation.",

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AU - Kang, Soonchul

AU - Kanegawa, Shinji

AU - Sato, Osamu

PY - 2012/11/28

Y1 - 2012/11/28

N2 - The reaction of Co(NO3)2·6H2O and 3-benzoylpyridine with the low-spin iron(iii) complex, H[FeIII(phen) (CN)4], in methanol gives rise to a cyanide-bridged heterobimetallic chain [{FeIII(phen)(CN)4}2Co II(3-bpe)2] (1) that exhibits intrachain ferromagnetic coupling and slow double magnetic relaxation.

AB - The reaction of Co(NO3)2·6H2O and 3-benzoylpyridine with the low-spin iron(iii) complex, H[FeIII(phen) (CN)4], in methanol gives rise to a cyanide-bridged heterobimetallic chain [{FeIII(phen)(CN)4}2Co II(3-bpe)2] (1) that exhibits intrachain ferromagnetic coupling and slow double magnetic relaxation.

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JO - Dalton Transactions

JF - Dalton Transactions

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ER -

Slow magnetic relaxation in a 4,2-ribbon like Fe^III ₂Co^II heterobimetallic chain

Abstract

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