Selective reduction of carboxylic acids to aldehydes by a ruthenium-catalyzed reaction with 1,2-bis(dimethylsilyl)benzene

Konoka Miyamoto; Yukihiro Motoyama; Hideo Nagashima

doi:10.1246/cl.2012.229

Selective reduction of carboxylic acids to aldehydes by a ruthenium-catalyzed reaction with 1,2-bis(dimethylsilyl)benzene

Konoka Miyamoto, Yukihiro Motoyama, Hideo Nagashima

Department of Applied Molecular Chemistry

Research output: Contribution to journal › Article › peer-review

34 Citations (Scopus)

Abstract

Novel transformation of carboxylic acids to aldehydes is achieved by a one-pot procedure consisting of a rutheniumcatalyzed hydrosilane reduction with 1,2-bis(dimethylsilyl)benzene (2) followed by hydrolysis of the resulting cyclic disilylacetals 4.

Original language	English
Pages (from-to)	229-231
Number of pages	3
Journal	Chemistry Letters
Volume	41
Issue number	3
DOIs	https://doi.org/10.1246/cl.2012.229
Publication status	Published - 2012

All Science Journal Classification (ASJC) codes

Chemistry(all)

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10.1246/cl.2012.229

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title = "Selective reduction of carboxylic acids to aldehydes by a ruthenium-catalyzed reaction with 1,2-bis(dimethylsilyl)benzene",

abstract = "Novel transformation of carboxylic acids to aldehydes is achieved by a one-pot procedure consisting of a rutheniumcatalyzed hydrosilane reduction with 1,2-bis(dimethylsilyl)benzene (2) followed by hydrolysis of the resulting cyclic disilylacetals 4.",

author = "Konoka Miyamoto and Yukihiro Motoyama and Hideo Nagashima",

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doi = "10.1246/cl.2012.229",

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journal = "Chemistry Letters",

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publisher = "The Chemical Society of Japan",

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AU - Nagashima, Hideo

PY - 2012

Y1 - 2012

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AB - Novel transformation of carboxylic acids to aldehydes is achieved by a one-pot procedure consisting of a rutheniumcatalyzed hydrosilane reduction with 1,2-bis(dimethylsilyl)benzene (2) followed by hydrolysis of the resulting cyclic disilylacetals 4.

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AN - SCOPUS:84857283138

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IS - 3

ER -

Selective reduction of carboxylic acids to aldehydes by a ruthenium-catalyzed reaction with 1,2-bis(dimethylsilyl)benzene

Abstract

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