Selective iodide chemosensing through a redox-active Cu-corrole

Biju Basumatary; Masood Ayoub Kaloo; Vineet Kumar Singh; Ruchika Mishra; Muthuchamy Murugavel; Jeyaraman Sankar

doi:10.1039/c4ra04191g

Selective iodide chemosensing through a redox-active Cu-corrole

Biju Basumatary, Masood Ayoub Kaloo, Vineet Kumar Singh, Ruchika Mishra, Muthuchamy Murugavel, Jeyaraman Sankar

Research output: Contribution to journal › Article › peer-review

17 Citations (Scopus)

Abstract

An electron deficient Cu(iii)-corrole (B) has been identified as a highly selective colorimetric sensor for iodide. A one-electron redox couple between iodide and Cu(iii)-corrole serves as the basis for selectivity. The proposed mechanism has been supported by UV-vis and ¹⁹F NMR studies and further by unambiguous identification of Cu(ii) species through EPR.

Original language	English
Pages (from-to)	28417-28420
Number of pages	4
Journal	RSC Advances
Volume	4
Issue number	54
DOIs	https://doi.org/10.1039/c4ra04191g
Publication status	Published - 2014
Externally published	Yes

All Science Journal Classification (ASJC) codes

Chemistry(all)
Chemical Engineering(all)

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10.1039/c4ra04191g

Cite this

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abstract = "An electron deficient Cu(iii)-corrole (B) has been identified as a highly selective colorimetric sensor for iodide. A one-electron redox couple between iodide and Cu(iii)-corrole serves as the basis for selectivity. The proposed mechanism has been supported by UV-vis and 19F NMR studies and further by unambiguous identification of Cu(ii) species through EPR.",

author = "Biju Basumatary and {Ayoub Kaloo}, Masood and {Kumar Singh}, Vineet and Ruchika Mishra and Muthuchamy Murugavel and Jeyaraman Sankar",

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T1 - Selective iodide chemosensing through a redox-active Cu-corrole

AU - Basumatary, Biju

AU - Ayoub Kaloo, Masood

AU - Kumar Singh, Vineet

AU - Mishra, Ruchika

AU - Murugavel, Muthuchamy

AU - Sankar, Jeyaraman

PY - 2014

Y1 - 2014

N2 - An electron deficient Cu(iii)-corrole (B) has been identified as a highly selective colorimetric sensor for iodide. A one-electron redox couple between iodide and Cu(iii)-corrole serves as the basis for selectivity. The proposed mechanism has been supported by UV-vis and 19F NMR studies and further by unambiguous identification of Cu(ii) species through EPR.

AB - An electron deficient Cu(iii)-corrole (B) has been identified as a highly selective colorimetric sensor for iodide. A one-electron redox couple between iodide and Cu(iii)-corrole serves as the basis for selectivity. The proposed mechanism has been supported by UV-vis and 19F NMR studies and further by unambiguous identification of Cu(ii) species through EPR.

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U2 - 10.1039/c4ra04191g

DO - 10.1039/c4ra04191g

M3 - Article

AN - SCOPUS:84903974390

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EP - 28420

JO - RSC Advances

JF - RSC Advances

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ER -

Selective iodide chemosensing through a redox-active Cu-corrole

Abstract

All Science Journal Classification (ASJC) codes

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