Selective cine substitution of 1-arylethenyl acetates with arylboron reagents and a diene/rhodium catalyst

Jung Yi Yu; Ryosuke Shimizu; Ryoichi Kuwano

doi:10.1002/anie.201002745

Selective cine substitution of 1-arylethenyl acetates with arylboron reagents and a diene/rhodium catalyst

Jung Yi Yu, Ryosuke Shimizu, Ryoichi Kuwano

Multidisciplinary chemistry

Research output: Contribution to journal › Article › peer-review

40 Citations (Scopus)

Abstract

When the crowd says Bo: A carbon-carbon bond is selectively formed at the β position of 1- arylethenyl acetate when the alkenyl substrate is reacted with arylboronic acids in the presence of a cycloocta-1,5-diene/rhodium catalyst. The choice of the ligand is crucial for the unusual cine substitution.

Original language	English
Pages (from-to)	6396-6399
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	49
Issue number	36
DOIs	https://doi.org/10.1002/anie.201002745
Publication status	Published - Aug 23 2010

All Science Journal Classification (ASJC) codes

General Chemistry
Catalysis

Access to Document

10.1002/anie.201002745

Cite this

@article{3ec413d1631a4fee980b074e142a5fe8,

title = "Selective cine substitution of 1-arylethenyl acetates with arylboron reagents and a diene/rhodium catalyst",

abstract = "When the crowd says Bo: A carbon-carbon bond is selectively formed at the β position of 1- arylethenyl acetate when the alkenyl substrate is reacted with arylboronic acids in the presence of a cycloocta-1,5-diene/rhodium catalyst. The choice of the ligand is crucial for the unusual cine substitution.",

author = "Yu, {Jung Yi} and Ryosuke Shimizu and Ryoichi Kuwano",

year = "2010",

month = aug,

day = "23",

doi = "10.1002/anie.201002745",

language = "English",

volume = "49",

pages = "6396--6399",

journal = "Angewandte Chemie - International Edition",

issn = "1433-7851",

publisher = "John Wiley and Sons Ltd",

number = "36",

}

TY - JOUR

T1 - Selective cine substitution of 1-arylethenyl acetates with arylboron reagents and a diene/rhodium catalyst

AU - Yu, Jung Yi

AU - Shimizu, Ryosuke

AU - Kuwano, Ryoichi

PY - 2010/8/23

Y1 - 2010/8/23

N2 - When the crowd says Bo: A carbon-carbon bond is selectively formed at the β position of 1- arylethenyl acetate when the alkenyl substrate is reacted with arylboronic acids in the presence of a cycloocta-1,5-diene/rhodium catalyst. The choice of the ligand is crucial for the unusual cine substitution.

AB - When the crowd says Bo: A carbon-carbon bond is selectively formed at the β position of 1- arylethenyl acetate when the alkenyl substrate is reacted with arylboronic acids in the presence of a cycloocta-1,5-diene/rhodium catalyst. The choice of the ligand is crucial for the unusual cine substitution.

UR - http://www.scopus.com/inward/record.url?scp=77956033162&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=77956033162&partnerID=8YFLogxK

U2 - 10.1002/anie.201002745

DO - 10.1002/anie.201002745

M3 - Article

C2 - 20652924

AN - SCOPUS:77956033162

SN - 1433-7851

VL - 49

SP - 6396

EP - 6399

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 36

ER -

Selective cine substitution of 1-arylethenyl acetates with arylboron reagents and a diene/rhodium catalyst

Abstract

All Science Journal Classification (ASJC) codes

Access to Document

Other files and links

Fingerprint

Cite this