Saccharide control of energy-transfer luminescence of lanthanide ions encapsulated in calix[4]arenes: A novel discrimination method for the energy-transfer route

Hitoshi Matsumoto; Aiichiro Ori; Fumiaki Inokuchi; Seiji Shinkai

doi:10.1246/cl.1996.301

Saccharide control of energy-transfer luminescence of lanthanide ions encapsulated in calix[4]arenes: A novel discrimination method for the energy-transfer route

Hitoshi Matsumoto, Aiichiro Ori, Fumiaki Inokuchi, Seiji Shinkai

Research output: Contribution to journal › Article › peer-review

7 Citations (Scopus)

Abstract

A calix[4]arene bearing three amide groups (composing a lanthanide binding site) and one sensitizer (phenacyl group) bearing an (o-boronylphenyl)methylaminomethyl group (acting as a sugar-binding site) was synthesized. The energy-transfer to Eu³⁺ was significantly enhanced whereas that to Tb³⁺ was only slightly enhanced, indicating that in the Eu³⁺ complex the energy is mainly transferred from the sensitizer whereas in the Tb³⁺ complex it is mainly transferred from the calix[4]arene aromatic rings. This is a novel method for discriminating the energy-transfer path.

Original language	English
Pages (from-to)	301-302
Number of pages	2
Journal	Chemistry Letters
Issue number	4
DOIs	https://doi.org/10.1246/cl.1996.301
Publication status	Published - 1996
Externally published	Yes

All Science Journal Classification (ASJC) codes

Chemistry(all)

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10.1246/cl.1996.301

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title = "Saccharide control of energy-transfer luminescence of lanthanide ions encapsulated in calix[4]arenes: A novel discrimination method for the energy-transfer route",

abstract = "A calix[4]arene bearing three amide groups (composing a lanthanide binding site) and one sensitizer (phenacyl group) bearing an (o-boronylphenyl)methylaminomethyl group (acting as a sugar-binding site) was synthesized. The energy-transfer to Eu3+ was significantly enhanced whereas that to Tb3+ was only slightly enhanced, indicating that in the Eu3+ complex the energy is mainly transferred from the sensitizer whereas in the Tb3+ complex it is mainly transferred from the calix[4]arene aromatic rings. This is a novel method for discriminating the energy-transfer path.",

author = "Hitoshi Matsumoto and Aiichiro Ori and Fumiaki Inokuchi and Seiji Shinkai",

year = "1996",

doi = "10.1246/cl.1996.301",

language = "English",

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journal = "Chemistry Letters",

issn = "0366-7022",

publisher = "The Chemical Society of Japan",

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T1 - Saccharide control of energy-transfer luminescence of lanthanide ions encapsulated in calix[4]arenes

T2 - A novel discrimination method for the energy-transfer route

AU - Matsumoto, Hitoshi

AU - Ori, Aiichiro

AU - Inokuchi, Fumiaki

AU - Shinkai, Seiji

PY - 1996

Y1 - 1996

N2 - A calix[4]arene bearing three amide groups (composing a lanthanide binding site) and one sensitizer (phenacyl group) bearing an (o-boronylphenyl)methylaminomethyl group (acting as a sugar-binding site) was synthesized. The energy-transfer to Eu3+ was significantly enhanced whereas that to Tb3+ was only slightly enhanced, indicating that in the Eu3+ complex the energy is mainly transferred from the sensitizer whereas in the Tb3+ complex it is mainly transferred from the calix[4]arene aromatic rings. This is a novel method for discriminating the energy-transfer path.

AB - A calix[4]arene bearing three amide groups (composing a lanthanide binding site) and one sensitizer (phenacyl group) bearing an (o-boronylphenyl)methylaminomethyl group (acting as a sugar-binding site) was synthesized. The energy-transfer to Eu3+ was significantly enhanced whereas that to Tb3+ was only slightly enhanced, indicating that in the Eu3+ complex the energy is mainly transferred from the sensitizer whereas in the Tb3+ complex it is mainly transferred from the calix[4]arene aromatic rings. This is a novel method for discriminating the energy-transfer path.

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ER -

Saccharide control of energy-transfer luminescence of lanthanide ions encapsulated in calix[4]arenes: A novel discrimination method for the energy-transfer route

Abstract

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