Ruthenium-catalyzed selective and efficient oxygenation of hydrocarbons with water as an oxygen source

Yuichirou Hirai; Takahiko Kojima; Yasuhisa Mizutani; Yoshihito Shiota; Kazunari Yoshizawa; Shunichi Fukuzumi

doi:10.1002/anie.200801170

Ruthenium-catalyzed selective and efficient oxygenation of hydrocarbons with water as an oxygen source

Yuichirou Hirai, Takahiko Kojima, Yasuhisa Mizutani, Yoshihito Shiota, Kazunari Yoshizawa, Shunichi Fukuzumi

Department of Fundamental Organic Chemistry

Research output: Contribution to journal › Article › peer-review

125 Citations (Scopus)

Abstract

(Chemical Equation Presented) Water is not only the solvent but also the sole oxygen source in the smooth and efficient oxidation of organic compounds catalyzed by a Ru^II-pyridylamine-aqua complex with Ce^IV as the oxidant. An intermediate-spin Ru^IV-oxo complex is formed as the reactive species (see scheme; Sub = substrate). This catalytic system is durable and able to gain high turnover numbers for various substrates.

Original language	English
Pages (from-to)	5772-5776
Number of pages	5
Journal	Angewandte Chemie - International Edition
Volume	47
Issue number	31
DOIs	https://doi.org/10.1002/anie.200801170
Publication status	Published - Jul 21 2008

All Science Journal Classification (ASJC) codes

Catalysis
Chemistry(all)

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10.1002/anie.200801170

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abstract = "(Chemical Equation Presented) Water is not only the solvent but also the sole oxygen source in the smooth and efficient oxidation of organic compounds catalyzed by a RuII-pyridylamine-aqua complex with CeIV as the oxidant. An intermediate-spin RuIV-oxo complex is formed as the reactive species (see scheme; Sub = substrate). This catalytic system is durable and able to gain high turnover numbers for various substrates.",

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T1 - Ruthenium-catalyzed selective and efficient oxygenation of hydrocarbons with water as an oxygen source

AU - Hirai, Yuichirou

AU - Kojima, Takahiko

AU - Mizutani, Yasuhisa

AU - Shiota, Yoshihito

AU - Yoshizawa, Kazunari

AU - Fukuzumi, Shunichi

PY - 2008/7/21

Y1 - 2008/7/21

N2 - (Chemical Equation Presented) Water is not only the solvent but also the sole oxygen source in the smooth and efficient oxidation of organic compounds catalyzed by a RuII-pyridylamine-aqua complex with CeIV as the oxidant. An intermediate-spin RuIV-oxo complex is formed as the reactive species (see scheme; Sub = substrate). This catalytic system is durable and able to gain high turnover numbers for various substrates.

AB - (Chemical Equation Presented) Water is not only the solvent but also the sole oxygen source in the smooth and efficient oxidation of organic compounds catalyzed by a RuII-pyridylamine-aqua complex with CeIV as the oxidant. An intermediate-spin RuIV-oxo complex is formed as the reactive species (see scheme; Sub = substrate). This catalytic system is durable and able to gain high turnover numbers for various substrates.

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JF - Angewandte Chemie - International Edition

IS - 31

ER -

Ruthenium-catalyzed selective and efficient oxygenation of hydrocarbons with water as an oxygen source

Abstract

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