Room temperature synthesis of anti-perovskite structured Li2OHBr

Manoj Krishna Sugumar, Takayuki Yamamoto, Munekazu Motoyama, Yasutoshi Iriyama

Research output: Contribution to journalArticlepeer-review

24 Citations (Scopus)

Abstract

Lithium-rich anti-perovskite (LiRAP) structured Li+ conductors are soft and have been reported to be potentially high Li+ conductive material. This article reports a novel synthesis method to fabricate Li2OHBr, a partially hydrated LiRAP, at room temperature just by ball milling of LiOH and LiBr powders. The resultant Li2OHBr was formed as cubic-phase (a = 4.046 Å) with melting point at 254 °C. Lithium-ion conductivity of the Li2OHBr was 1.1 × 10−6 S cm−1 at 25 °C with the activation energy of 0.54 eV. The resultant Li2OHBr repeated stable lithium plating/stripping reactions for 100 cycles at 60 °C with 50 μA cm−2.

Original languageEnglish
Article number115298
JournalSolid State Ionics
Volume349
DOIs
Publication statusPublished - Jun 2020
Externally publishedYes

All Science Journal Classification (ASJC) codes

  • General Chemistry
  • General Materials Science
  • Condensed Matter Physics

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