Rhodium catalyzed transformation of propargylamines to 2-silylmethyl-2-alkenals: Formal silylformylation of allenes

Isamu Matsuda; Jun Sakakibara; Hirofumi Inoue; Hideo Nagashima

doi:10.1016/0040-4039(92)89035-B

Rhodium catalyzed transformation of propargylamines to 2-silylmethyl-2-alkenals: Formal silylformylation of allenes

Isamu Matsuda, Jun Sakakibara, Hirofumi Inoue, Hideo Nagashima

Research output: Contribution to journal › Article › peer-review

44 Citations (Scopus)

Abstract

Propargylamines are effectively transformed to 2-dimethylphenylsilylmethyl-2-alkenals by the interaction of two equivalents of Me₂PhSiH under silylformylation conditions catalyzed by Rh₄(CO)₁₂. The products are not obtained directly by silylformylation of the corresponding allenes.

Original language	English
Pages (from-to)	5799-5802
Number of pages	4
Journal	Tetrahedron Letters
Volume	33
Issue number	39
DOIs	https://doi.org/10.1016/0040-4039(92)89035-B
Publication status	Published - Sept 22 1992
Externally published	Yes

All Science Journal Classification (ASJC) codes

Biochemistry
Drug Discovery
Organic Chemistry

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10.1016/0040-4039(92)89035-B

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title = "Rhodium catalyzed transformation of propargylamines to 2-silylmethyl-2-alkenals: Formal silylformylation of allenes",

abstract = "Propargylamines are effectively transformed to 2-dimethylphenylsilylmethyl-2-alkenals by the interaction of two equivalents of Me2PhSiH under silylformylation conditions catalyzed by Rh4(CO)12. The products are not obtained directly by silylformylation of the corresponding allenes.",

author = "Isamu Matsuda and Jun Sakakibara and Hirofumi Inoue and Hideo Nagashima",

year = "1992",

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doi = "10.1016/0040-4039(92)89035-B",

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T1 - Rhodium catalyzed transformation of propargylamines to 2-silylmethyl-2-alkenals

T2 - Formal silylformylation of allenes

AU - Matsuda, Isamu

AU - Sakakibara, Jun

AU - Inoue, Hirofumi

AU - Nagashima, Hideo

PY - 1992/9/22

Y1 - 1992/9/22

N2 - Propargylamines are effectively transformed to 2-dimethylphenylsilylmethyl-2-alkenals by the interaction of two equivalents of Me2PhSiH under silylformylation conditions catalyzed by Rh4(CO)12. The products are not obtained directly by silylformylation of the corresponding allenes.

AB - Propargylamines are effectively transformed to 2-dimethylphenylsilylmethyl-2-alkenals by the interaction of two equivalents of Me2PhSiH under silylformylation conditions catalyzed by Rh4(CO)12. The products are not obtained directly by silylformylation of the corresponding allenes.

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JO - Tetrahedron Letters

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Rhodium catalyzed transformation of propargylamines to 2-silylmethyl-2-alkenals: Formal silylformylation of allenes

Abstract

All Science Journal Classification (ASJC) codes

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