TY - JOUR
T1 - Rhodium-catalyzed thiophosphinoylation reaction of 1,2-dienes with diphosphine disulfides
AU - Arisawa, Mieko
AU - Yamaguchi, Masahiko
N1 - Funding Information:
This work was supported by JSPS (Nos. 16109001 and 17689001). M.A. expresses her thanks to the Grant-in-Aid for Scientific Research on Priority Areas, ‘Advanced Molecular Transformation of Carbon Resources’ from MEXT (Nos. 18037005 and 19020008).
PY - 2009/1/7
Y1 - 2009/1/7
N2 - In the presence of RhH(PPh3)4, the reaction of 1,2-alkadienes, tetramethyldiphosphine disulfide, and camphorsulfonic acid gave (E)-2-dimethylthiophosphinoyl-2-alkenes. The reaction involved the P-P cleavage and the transfer of the thiophosphinoyl group to 1,2-alkadienes with concomitant formation of thiophosphinic anhydride.
AB - In the presence of RhH(PPh3)4, the reaction of 1,2-alkadienes, tetramethyldiphosphine disulfide, and camphorsulfonic acid gave (E)-2-dimethylthiophosphinoyl-2-alkenes. The reaction involved the P-P cleavage and the transfer of the thiophosphinoyl group to 1,2-alkadienes with concomitant formation of thiophosphinic anhydride.
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U2 - 10.1016/j.tetlet.2008.10.075
DO - 10.1016/j.tetlet.2008.10.075
M3 - Article
AN - SCOPUS:57049099740
SN - 0040-4039
VL - 50
SP - 45
EP - 47
JO - Tetrahedron Letters
JF - Tetrahedron Letters
IS - 1
ER -