TY - JOUR
T1 - Rhodium-Catalyzed Synthesis of Unsymmetric Di(heteroaryl) Sulfides Using Heteroaryl Ethers and S-Heteroaryl Thioesters via Heteroarylthio Exchange
AU - Arisawa, Mieko
AU - Tazawa, Takeru
AU - Tanii, Saori
AU - Horiuchi, Kiyofumi
AU - Yamaguchi, Masahiko
N1 - Publisher Copyright:
© 2016 American Chemical Society.
PY - 2017/1/6
Y1 - 2017/1/6
N2 - Unsymmetric di(heteroaryl) sulfides were synthesized by a rhodium-catalyzed heteroarylthio exchange reaction of heteroaryl aryl ethers and S-(heteroaryl) thioesters. The reaction has broad applicability, giving diverse unsymmetric di(heteroaryl) sulfides containing five- and six-membered heteroarenes. No base is required in this reaction, which has been developed by the judicious design of organic substrates.
AB - Unsymmetric di(heteroaryl) sulfides were synthesized by a rhodium-catalyzed heteroarylthio exchange reaction of heteroaryl aryl ethers and S-(heteroaryl) thioesters. The reaction has broad applicability, giving diverse unsymmetric di(heteroaryl) sulfides containing five- and six-membered heteroarenes. No base is required in this reaction, which has been developed by the judicious design of organic substrates.
UR - http://www.scopus.com/inward/record.url?scp=85018512105&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=85018512105&partnerID=8YFLogxK
U2 - 10.1021/acs.joc.6b02585
DO - 10.1021/acs.joc.6b02585
M3 - Article
C2 - 27936692
AN - SCOPUS:85018512105
SN - 0022-3263
VL - 82
SP - 804
EP - 810
JO - Journal of Organic Chemistry
JF - Journal of Organic Chemistry
IS - 1
ER -