TY - JOUR
T1 - Rhodium-Catalyzed Synthesis of Heteroarylselenyl Esters from Diheteroaryl Diselenides and Acid Fluorides
AU - Arisawa, Mieko
AU - Suzuki, Ren
AU - Ohashi, Keiichiro
AU - Yamaguchi, Masahiko
N1 - Funding Information:
This research was supported by the Platform Project for Supporting Drug Discovery and Life Science Research from AMED (Grant Number JP19am0101100) and Tohoku University Center for Gender Equality Promotion (TUMUG).
Publisher Copyright:
© 2020 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim
PY - 2020/4/1
Y1 - 2020/4/1
N2 - A rhodium complex catalyzed C−Se bond formation between diheteroaryl diselenides and acid fluorides in the presence of triphenylphosphine to provide heteroarylselenyl esters in good yields. The reaction was applicable to five- and six-membered heteroaryl compounds. The heteroarylselenyl esters can be used as heteroaryselenating reagents in the synthesis of heteroaryl selenides, as shown by a platinum-catalyzed addition reaction with 1-octyne.
AB - A rhodium complex catalyzed C−Se bond formation between diheteroaryl diselenides and acid fluorides in the presence of triphenylphosphine to provide heteroarylselenyl esters in good yields. The reaction was applicable to five- and six-membered heteroaryl compounds. The heteroarylselenyl esters can be used as heteroaryselenating reagents in the synthesis of heteroaryl selenides, as shown by a platinum-catalyzed addition reaction with 1-octyne.
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U2 - 10.1002/ajoc.202000077
DO - 10.1002/ajoc.202000077
M3 - Article
AN - SCOPUS:85080110775
SN - 2193-5807
VL - 9
SP - 553
EP - 556
JO - Asian Journal of Organic Chemistry
JF - Asian Journal of Organic Chemistry
IS - 4
ER -