Rhodium-catalyzed synthesis of 1-alkynylphosphine oxides from 1-alkynes and tetraphenylbiphosphine

Mieko Arisawa; Masato Onoda; Chieko Hori; Masahiko Yamaguchi

doi:10.1016/j.tetlet.2006.04.158

Rhodium-catalyzed synthesis of 1-alkynylphosphine oxides from 1-alkynes and tetraphenylbiphosphine

Mieko Arisawa, Masato Onoda, Chieko Hori, Masahiko Yamaguchi

Research output: Contribution to journal › Article › peer-review

27 Citations (Scopus)

Abstract

A rhodium complex RhH(PPh₃)₄ catalyzes the C-P bond forming reaction of 1-alkynes and tetraphenylbiphosphine in the presence of 2,4-dimethylnitrobenzene giving 1-alkynylphosphines and its oxides.

Original language	English
Pages (from-to)	5211-5213
Number of pages	3
Journal	Tetrahedron Letters
Volume	47
Issue number	29
DOIs	https://doi.org/10.1016/j.tetlet.2006.04.158
Publication status	Published - Jul 17 2006
Externally published	Yes

All Science Journal Classification (ASJC) codes

Biochemistry
Drug Discovery
Organic Chemistry

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10.1016/j.tetlet.2006.04.158

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title = "Rhodium-catalyzed synthesis of 1-alkynylphosphine oxides from 1-alkynes and tetraphenylbiphosphine",

abstract = "A rhodium complex RhH(PPh3)4 catalyzes the C-P bond forming reaction of 1-alkynes and tetraphenylbiphosphine in the presence of 2,4-dimethylnitrobenzene giving 1-alkynylphosphines and its oxides.",

author = "Mieko Arisawa and Masato Onoda and Chieko Hori and Masahiko Yamaguchi",

note = "Funding Information: M.A. expresses her thanks to the Grant-in-Aid for Scientific Research on Priority Areas, {\textquoteleft}Advanced Molecular Transformation of Carbon Resources{\textquoteright} from MEXT (No. 18037005). This work was supported also by JSPS (Nos. 16109001 and 17689001).",

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doi = "10.1016/j.tetlet.2006.04.158",

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T1 - Rhodium-catalyzed synthesis of 1-alkynylphosphine oxides from 1-alkynes and tetraphenylbiphosphine

AU - Arisawa, Mieko

AU - Onoda, Masato

AU - Hori, Chieko

AU - Yamaguchi, Masahiko

N1 - Funding Information: M.A. expresses her thanks to the Grant-in-Aid for Scientific Research on Priority Areas, ‘Advanced Molecular Transformation of Carbon Resources’ from MEXT (No. 18037005). This work was supported also by JSPS (Nos. 16109001 and 17689001).

PY - 2006/7/17

Y1 - 2006/7/17

N2 - A rhodium complex RhH(PPh3)4 catalyzes the C-P bond forming reaction of 1-alkynes and tetraphenylbiphosphine in the presence of 2,4-dimethylnitrobenzene giving 1-alkynylphosphines and its oxides.

AB - A rhodium complex RhH(PPh3)4 catalyzes the C-P bond forming reaction of 1-alkynes and tetraphenylbiphosphine in the presence of 2,4-dimethylnitrobenzene giving 1-alkynylphosphines and its oxides.

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U2 - 10.1016/j.tetlet.2006.04.158

DO - 10.1016/j.tetlet.2006.04.158

M3 - Article

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EP - 5213

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 29

ER -

Rhodium-catalyzed synthesis of 1-alkynylphosphine oxides from 1-alkynes and tetraphenylbiphosphine

Abstract

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