Rhodium-catalyzed Beckmann rearrangement

Mieko Arisawa; Masahiko Yamaguchi

doi:10.1021/ol006951z

Rhodium-catalyzed Beckmann rearrangement

Mieko Arisawa, Masahiko Yamaguchi

Research output: Contribution to journal › Article › peer-review

84 Citations (Scopus)

Abstract

equation presented Beckmann rearrangement of oxime is catalyzed by [RhCl(cod)]₂, trifluoromethanesulfonic acid, and tris(p-tolyl)phosphine in refluxing dichloroethane, giving the corresponding amide in good yield. Product/acid ratios of 10:20 can be attained in the reaction of benzophenone oximes.

Original language	English
Pages (from-to)	311-312
Number of pages	2
Journal	Organic letters
Volume	3
Issue number	2
DOIs	https://doi.org/10.1021/ol006951z
Publication status	Published - Jan 25 2001
Externally published	Yes

All Science Journal Classification (ASJC) codes

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry

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10.1021/ol006951z

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title = "Rhodium-catalyzed Beckmann rearrangement",

abstract = "equation presented Beckmann rearrangement of oxime is catalyzed by [RhCl(cod)]2, trifluoromethanesulfonic acid, and tris(p-tolyl)phosphine in refluxing dichloroethane, giving the corresponding amide in good yield. Product/acid ratios of 10:20 can be attained in the reaction of benzophenone oximes.",

author = "Mieko Arisawa and Masahiko Yamaguchi",

year = "2001",

month = jan,

day = "25",

doi = "10.1021/ol006951z",

language = "English",

volume = "3",

pages = "311--312",

journal = "Organic letters",

issn = "1523-7060",

publisher = "American Chemical Society",

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T1 - Rhodium-catalyzed Beckmann rearrangement

AU - Arisawa, Mieko

AU - Yamaguchi, Masahiko

PY - 2001/1/25

Y1 - 2001/1/25

N2 - equation presented Beckmann rearrangement of oxime is catalyzed by [RhCl(cod)]2, trifluoromethanesulfonic acid, and tris(p-tolyl)phosphine in refluxing dichloroethane, giving the corresponding amide in good yield. Product/acid ratios of 10:20 can be attained in the reaction of benzophenone oximes.

AB - equation presented Beckmann rearrangement of oxime is catalyzed by [RhCl(cod)]2, trifluoromethanesulfonic acid, and tris(p-tolyl)phosphine in refluxing dichloroethane, giving the corresponding amide in good yield. Product/acid ratios of 10:20 can be attained in the reaction of benzophenone oximes.

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DO - 10.1021/ol006951z

M3 - Article

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VL - 3

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JO - Organic letters

JF - Organic letters

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ER -

Rhodium-catalyzed Beckmann rearrangement

Abstract

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