Rhodium catalyzed anti-Markovnikov addition of triphenylphosphine to 1,3-dienes a novel method to separate pure (Z)-1,3-alkadienes from isomeric mixtures

Mieko Arisawa; Ryohei Momozuka; Masahiko Yamaguchi

doi:10.1246/cl.2002.272

Rhodium catalyzed anti-Markovnikov addition of triphenylphosphine to 1,3-dienes a novel method to separate pure (Z)-1,3-alkadienes from isomeric mixtures

Mieko Arisawa, Ryohei Momozuka, Masahiko Yamaguchi

Research output: Contribution to journal › Article › peer-review

7 Citations (Scopus)

Abstract

Rhodium-catalyzed addition of triphenylphosphine and trifluoromethanesulfonic acid to (E)-1,3-dienes gives (E)-3-alkenylphosphonium salts in the anti-Markovnikov mode. The addition reactions to (E)-1,3-dienes proceed more rapidly than those to (Z)-1,3-dienes, which can be utilized to separate pure (Z)-1,3-dienes from isomeric mixtures.

Original language	English
Pages (from-to)	272-273
Number of pages	2
Journal	Chemistry Letters
Issue number	3
DOIs	https://doi.org/10.1246/cl.2002.272
Publication status	Published - Mar 5 2002
Externally published	Yes

All Science Journal Classification (ASJC) codes

Chemistry(all)

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10.1246/cl.2002.272

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abstract = "Rhodium-catalyzed addition of triphenylphosphine and trifluoromethanesulfonic acid to (E)-1,3-dienes gives (E)-3-alkenylphosphonium salts in the anti-Markovnikov mode. The addition reactions to (E)-1,3-dienes proceed more rapidly than those to (Z)-1,3-dienes, which can be utilized to separate pure (Z)-1,3-dienes from isomeric mixtures.",

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doi = "10.1246/cl.2002.272",

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journal = "Chemistry Letters",

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AU - Momozuka, Ryohei

AU - Yamaguchi, Masahiko

PY - 2002/3/5

Y1 - 2002/3/5

N2 - Rhodium-catalyzed addition of triphenylphosphine and trifluoromethanesulfonic acid to (E)-1,3-dienes gives (E)-3-alkenylphosphonium salts in the anti-Markovnikov mode. The addition reactions to (E)-1,3-dienes proceed more rapidly than those to (Z)-1,3-dienes, which can be utilized to separate pure (Z)-1,3-dienes from isomeric mixtures.

AB - Rhodium-catalyzed addition of triphenylphosphine and trifluoromethanesulfonic acid to (E)-1,3-dienes gives (E)-3-alkenylphosphonium salts in the anti-Markovnikov mode. The addition reactions to (E)-1,3-dienes proceed more rapidly than those to (Z)-1,3-dienes, which can be utilized to separate pure (Z)-1,3-dienes from isomeric mixtures.

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Rhodium catalyzed anti-Markovnikov addition of triphenylphosphine to 1,3-dienes a novel method to separate pure (Z)-1,3-alkadienes from isomeric mixtures

Abstract

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