Rhenium-templated regioselective polyhydrogenation reaction of [60]fullerene

Motoki Toganoh; Yutaka Matsuo; Eiichi Nakamura

doi:10.1002/anie.200351722

Rhenium-templated regioselective polyhydrogenation reaction of [60]fullerene

Motoki Toganoh, Yutaka Matsuo, Eiichi Nakamura

Research output: Contribution to journal › Article › peer-review

34 Citations (Scopus)

Abstract

Functionalizing fullerenes: The first regioselective polyhydrogenation of [60]fullerene has been achieved. Upon treatment of [60]fullerene or its derivative with 9,10-dihydroanthracene in the presence of [Re ₂(CO)₁₀], transfer hydrometallation reaction takes place to give a polyhydrogenation product (see scheme). The reaction provided a pathway to a variety of metal η⁵ complexes of hydrofullerenes.

Original language	English
Pages (from-to)	3530-3532
Number of pages	3
Journal	Angewandte Chemie - International Edition
Volume	42
Issue number	30
DOIs	https://doi.org/10.1002/anie.200351722
Publication status	Published - Aug 4 2003
Externally published	Yes

All Science Journal Classification (ASJC) codes

Catalysis
Chemistry(all)

Access to Document

10.1002/anie.200351722

Cite this

@article{55ec37670e77486390e0919412b831ad,

title = "Rhenium-templated regioselective polyhydrogenation reaction of [60]fullerene",

abstract = "Functionalizing fullerenes: The first regioselective polyhydrogenation of [60]fullerene has been achieved. Upon treatment of [60]fullerene or its derivative with 9,10-dihydroanthracene in the presence of [Re 2(CO)10], transfer hydrometallation reaction takes place to give a polyhydrogenation product (see scheme). The reaction provided a pathway to a variety of metal η5 complexes of hydrofullerenes.",

author = "Motoki Toganoh and Yutaka Matsuo and Eiichi Nakamura",

year = "2003",

month = aug,

day = "4",

doi = "10.1002/anie.200351722",

language = "English",

volume = "42",

pages = "3530--3532",

journal = "Angewandte Chemie - International Edition",

issn = "1433-7851",

publisher = "John Wiley and Sons Ltd",

number = "30",

}

TY - JOUR

T1 - Rhenium-templated regioselective polyhydrogenation reaction of [60]fullerene

AU - Toganoh, Motoki

AU - Matsuo, Yutaka

AU - Nakamura, Eiichi

PY - 2003/8/4

Y1 - 2003/8/4

N2 - Functionalizing fullerenes: The first regioselective polyhydrogenation of [60]fullerene has been achieved. Upon treatment of [60]fullerene or its derivative with 9,10-dihydroanthracene in the presence of [Re 2(CO)10], transfer hydrometallation reaction takes place to give a polyhydrogenation product (see scheme). The reaction provided a pathway to a variety of metal η5 complexes of hydrofullerenes.

AB - Functionalizing fullerenes: The first regioselective polyhydrogenation of [60]fullerene has been achieved. Upon treatment of [60]fullerene or its derivative with 9,10-dihydroanthracene in the presence of [Re 2(CO)10], transfer hydrometallation reaction takes place to give a polyhydrogenation product (see scheme). The reaction provided a pathway to a variety of metal η5 complexes of hydrofullerenes.

UR - http://www.scopus.com/inward/record.url?scp=0043032705&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0043032705&partnerID=8YFLogxK

U2 - 10.1002/anie.200351722

DO - 10.1002/anie.200351722

M3 - Article

C2 - 12900973

AN - SCOPUS:0043032705

SN - 1433-7851

VL - 42

SP - 3530

EP - 3532

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 30

ER -

Rhenium-templated regioselective polyhydrogenation reaction of [60]fullerene

Abstract

All Science Journal Classification (ASJC) codes

Access to Document

Other files and links

Fingerprint

Cite this