Rhenium-catalyzed addition of trimethylsilylacetylene to aldimines

Yoichiro Kuninobu; Yuichi Inoue; Kazuhiko Takai

doi:10.1246/cl.2006.1376

Rhenium-catalyzed addition of trimethylsilylacetylene to aldimines

Yoichiro Kuninobu, Yuichi Inoue, Kazuhiko Takai

Research output: Contribution to journal › Article › peer-review

31 Citations (Scopus)

Abstract

A rhenium complex, [ReBr(CO)₃(thf)]₂, catalyzes reactions of aldimines with trimethylsilylacetylene to give propargylamines in excellent yields. The reactions proceed at room temperature under solvent-free conditions.

Original language	English
Pages (from-to)	1376-1377
Number of pages	2
Journal	Chemistry Letters
Volume	35
Issue number	12
DOIs	https://doi.org/10.1246/cl.2006.1376
Publication status	Published - Dec 5 2006
Externally published	Yes

All Science Journal Classification (ASJC) codes

Chemistry(all)

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10.1246/cl.2006.1376

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title = "Rhenium-catalyzed addition of trimethylsilylacetylene to aldimines",

abstract = "A rhenium complex, [ReBr(CO)3(thf)]2, catalyzes reactions of aldimines with trimethylsilylacetylene to give propargylamines in excellent yields. The reactions proceed at room temperature under solvent-free conditions.",

author = "Yoichiro Kuninobu and Yuichi Inoue and Kazuhiko Takai",

year = "2006",

month = dec,

day = "5",

doi = "10.1246/cl.2006.1376",

language = "English",

volume = "35",

pages = "1376--1377",

journal = "Chemistry Letters",

issn = "0366-7022",

publisher = "The Chemical Society of Japan",

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AU - Kuninobu, Yoichiro

AU - Inoue, Yuichi

AU - Takai, Kazuhiko

PY - 2006/12/5

Y1 - 2006/12/5

N2 - A rhenium complex, [ReBr(CO)3(thf)]2, catalyzes reactions of aldimines with trimethylsilylacetylene to give propargylamines in excellent yields. The reactions proceed at room temperature under solvent-free conditions.

AB - A rhenium complex, [ReBr(CO)3(thf)]2, catalyzes reactions of aldimines with trimethylsilylacetylene to give propargylamines in excellent yields. The reactions proceed at room temperature under solvent-free conditions.

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VL - 35

SP - 1376

EP - 1377

JO - Chemistry Letters

JF - Chemistry Letters

IS - 12

ER -

Rhenium-catalyzed addition of trimethylsilylacetylene to aldimines

Abstract

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