Rhenium-catalysed dehydrogenative borylation of primary and secondary C(sp3)-H bonds adjacent to a nitrogen atom

Masahito Murai; Tetsuya Omura; Yoichiro Kuninobu; Kazuhiko Takai

doi:10.1039/c4cc09508a

Rhenium-catalysed dehydrogenative borylation of primary and secondary C(sp³)-H bonds adjacent to a nitrogen atom

Masahito Murai, Tetsuya Omura, Yoichiro Kuninobu, Kazuhiko Takai

Research output: Contribution to journal › Article › peer-review

29 Citations (Scopus)

Abstract

Rhenium-catalysed C(sp³)-H bond borylation in the absence of any oxidant, hydrogen acceptor, or external ligand, with the generation of H₂ as the sole byproduct is described. The transformation, which represents a rare example of rhenium-catalysed C(sp³)-H bond functionalisation, features high atom efficiency and simple reaction conditions. This journal is

Original language	English
Pages (from-to)	4583-4586
Number of pages	4
Journal	Chemical Communications
Volume	51
Issue number	22
DOIs	https://doi.org/10.1039/c4cc09508a
Publication status	Published - Mar 18 2015
Externally published	Yes

All Science Journal Classification (ASJC) codes

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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10.1039/c4cc09508a

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AU - Omura, Tetsuya

AU - Kuninobu, Yoichiro

AU - Takai, Kazuhiko

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Rhenium-catalysed dehydrogenative borylation of primary and secondary C(sp³)-H bonds adjacent to a nitrogen atom

Abstract

All Science Journal Classification (ASJC) codes

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