Reversibly crosslinked polymeric micelles formed by autonomously exchangeable dynamic covalent bonds

Masamichi Nishihara; Keiichi Imato; Atsushi Irie; Takeshi Kanehara; Arihiro Kano; Atsushi Maruyama; Atsushi Takahara; Hideyuki Otsuka

doi:10.1246/cl.121289

Reversibly crosslinked polymeric micelles formed by autonomously exchangeable dynamic covalent bonds

Masamichi Nishihara, Keiichi Imato, Atsushi Irie, Takeshi Kanehara, Arihiro Kano, Atsushi Maruyama, Atsushi Takahara, Hideyuki Otsuka

Research output: Contribution to journal › Article › peer-review

15 Citations (Scopus)

Abstract

We report the preparation of amphiphilic block copolymer micelles with dynamic covalent bonds as autonomously exchangeable crosslinkers with high tolerance against oxygen. Diarylbibenzofuranone (DABBF) was employed as a crosslinker owing to its durability to oxygen and autonomous exchangeability at ambient temperature. It was confirmed that the amphiphilic block copolymer containing the DABBF unit has the capability to form micelles and can form a crosslinking with an exchangeable structure in the presence of oxygen.

Original language	English
Pages (from-to)	377-379
Number of pages	3
Journal	Chemistry Letters
Volume	42
Issue number	4
DOIs	https://doi.org/10.1246/cl.121289
Publication status	Published - 2013

All Science Journal Classification (ASJC) codes

Chemistry(all)

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10.1246/cl.121289

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abstract = "We report the preparation of amphiphilic block copolymer micelles with dynamic covalent bonds as autonomously exchangeable crosslinkers with high tolerance against oxygen. Diarylbibenzofuranone (DABBF) was employed as a crosslinker owing to its durability to oxygen and autonomous exchangeability at ambient temperature. It was confirmed that the amphiphilic block copolymer containing the DABBF unit has the capability to form micelles and can form a crosslinking with an exchangeable structure in the presence of oxygen.",

author = "Masamichi Nishihara and Keiichi Imato and Atsushi Irie and Takeshi Kanehara and Arihiro Kano and Atsushi Maruyama and Atsushi Takahara and Hideyuki Otsuka",

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doi = "10.1246/cl.121289",

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AU - Nishihara, Masamichi

AU - Imato, Keiichi

AU - Irie, Atsushi

AU - Kanehara, Takeshi

AU - Kano, Arihiro

AU - Maruyama, Atsushi

AU - Takahara, Atsushi

AU - Otsuka, Hideyuki

PY - 2013

Y1 - 2013

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AB - We report the preparation of amphiphilic block copolymer micelles with dynamic covalent bonds as autonomously exchangeable crosslinkers with high tolerance against oxygen. Diarylbibenzofuranone (DABBF) was employed as a crosslinker owing to its durability to oxygen and autonomous exchangeability at ambient temperature. It was confirmed that the amphiphilic block copolymer containing the DABBF unit has the capability to form micelles and can form a crosslinking with an exchangeable structure in the presence of oxygen.

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JO - Chemistry Letters

JF - Chemistry Letters

IS - 4

ER -

Reversibly crosslinked polymeric micelles formed by autonomously exchangeable dynamic covalent bonds

Abstract

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