Remarkably high asymmetric amplification in the chiral lanthanide complex-catalyzed hetero-Diels - Alder reaction: First example of the nonlinear effect in ML3 system

Hiroshi Furuno; Takeshi Hanamoto; Yuichi Sugimoto; Junji Inanaga

Remarkably high asymmetric amplification in the chiral lanthanide complex-catalyzed hetero-Diels - Alder reaction: First example of the nonlinear effect in ML₃ system

Hiroshi Furuno, Takeshi Hanamoto, Yuichi Sugimoto, Junji Inanaga

Environmental Engineering Sciences

Research output: Contribution to journal › Article › peer-review

83 Citations (Scopus)

Abstract

(formula presented) A remarkably high asymmetric amplification was realized in the Yb[(R)-BNP]₃-catalyzed hetero-Diels - Alder reaction as the first example in the metal/chiral ligand 1:3 system. The mechanism may be explained by the autogenetic formation of the enantiopure complex as the most active catalyst. The enantiomer-discriminative formation of homochiral ML₃ complexes is quite general within the lanthanide metal ions with similar ionic radii to that of the ytterbium ion.

Original language	English
Pages (from-to)	49-52
Number of pages	4
Journal	Organic Letters
Volume	2
Issue number	1
Publication status	Published - Jan 1 2000

All Science Journal Classification (ASJC) codes

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry

Cite this

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title = "Remarkably high asymmetric amplification in the chiral lanthanide complex-catalyzed hetero-Diels - Alder reaction: First example of the nonlinear effect in ML3 system",

abstract = "(formula presented) A remarkably high asymmetric amplification was realized in the Yb[(R)-BNP]3-catalyzed hetero-Diels - Alder reaction as the first example in the metal/chiral ligand 1:3 system. The mechanism may be explained by the autogenetic formation of the enantiopure complex as the most active catalyst. The enantiomer-discriminative formation of homochiral ML3 complexes is quite general within the lanthanide metal ions with similar ionic radii to that of the ytterbium ion.",

author = "Hiroshi Furuno and Takeshi Hanamoto and Yuichi Sugimoto and Junji Inanaga",

year = "2000",

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language = "English",

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journal = "Organic Letters",

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T1 - Remarkably high asymmetric amplification in the chiral lanthanide complex-catalyzed hetero-Diels - Alder reaction

T2 - First example of the nonlinear effect in ML3 system

AU - Furuno, Hiroshi

AU - Hanamoto, Takeshi

AU - Sugimoto, Yuichi

AU - Inanaga, Junji

PY - 2000/1/1

Y1 - 2000/1/1

N2 - (formula presented) A remarkably high asymmetric amplification was realized in the Yb[(R)-BNP]3-catalyzed hetero-Diels - Alder reaction as the first example in the metal/chiral ligand 1:3 system. The mechanism may be explained by the autogenetic formation of the enantiopure complex as the most active catalyst. The enantiomer-discriminative formation of homochiral ML3 complexes is quite general within the lanthanide metal ions with similar ionic radii to that of the ytterbium ion.

AB - (formula presented) A remarkably high asymmetric amplification was realized in the Yb[(R)-BNP]3-catalyzed hetero-Diels - Alder reaction as the first example in the metal/chiral ligand 1:3 system. The mechanism may be explained by the autogenetic formation of the enantiopure complex as the most active catalyst. The enantiomer-discriminative formation of homochiral ML3 complexes is quite general within the lanthanide metal ions with similar ionic radii to that of the ytterbium ion.

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M3 - Article

AN - SCOPUS:0002004878

SN - 1523-7060

VL - 2

SP - 49

EP - 52

JO - Organic Letters

JF - Organic Letters

IS - 1

ER -

Remarkably high asymmetric amplification in the chiral lanthanide complex-catalyzed hetero-Diels - Alder reaction: First example of the nonlinear effect in ML₃ system

Abstract

All Science Journal Classification (ASJC) codes

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