Relative humidity-dependences of proton conductiVities of metal nanoparticles protected by rubeanic acid polymer

Musashi Fujishima; Ryuichi Ikeda; Takashi Kubo; Kazuhiro Nakasuji; Yuki Nagao; Miho Yamauchi; Yoshio Bando; Kumao Uchida; Hiroshi Kitagawa

Relative humidity-dependences of proton conductiVities of metal nanoparticles protected by rubeanic acid polymer

Musashi Fujishima, Ryuichi Ikeda, Takashi Kubo, Kazuhiro Nakasuji, Yuki Nagao, Miho Yamauchi, Yoshio Bando, Kumao Uchida, Hiroshi Kitagawa

Department of Applied Molecular Chemistry

Research output: Contribution to conference › Paper › peer-review

Abstract

The polymer-protected metal nanoparticle, characterized by a uniform particle size, a monodispersity and a large specific surface area with a chemical stability, has attracted much attention because of its potential application in the hydrogen technology. In this study, by use of a rubeanic acid polymer (RAP) with a dibasic acidic character, polymer-protected noble metal nanoparticles (RAP-Pt, RAP-Pd) with 4~15 nm diameters were successfully synthesized. Their proton conductivities at room temperature show relative humidity (RH)-dependences and reach at remarkably high value (>1×10^-2Scm^-1) at RH = 100 %. The mechanism of this phenomenon will be also described.

Original language	English
Pages	1716
Number of pages	1
Publication status	Published - 2005
Event	54th SPSJ Annual Meeting 2005 - Yokohama, Japan Duration: May 25 2005 → May 27 2005

Other

Other	54th SPSJ Annual Meeting 2005
Country/Territory	Japan
City	Yokohama
Period	5/25/05 → 5/27/05

All Science Journal Classification (ASJC) codes

Engineering(all)

Cite this

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title = "Relative humidity-dependences of proton conductiVities of metal nanoparticles protected by rubeanic acid polymer",

abstract = "The polymer-protected metal nanoparticle, characterized by a uniform particle size, a monodispersity and a large specific surface area with a chemical stability, has attracted much attention because of its potential application in the hydrogen technology. In this study, by use of a rubeanic acid polymer (RAP) with a dibasic acidic character, polymer-protected noble metal nanoparticles (RAP-Pt, RAP-Pd) with 4~15 nm diameters were successfully synthesized. Their proton conductivities at room temperature show relative humidity (RH)-dependences and reach at remarkably high value (>1×10-2Scm-1) at RH = 100 %. The mechanism of this phenomenon will be also described.",

author = "Musashi Fujishima and Ryuichi Ikeda and Takashi Kubo and Kazuhiro Nakasuji and Yuki Nagao and Miho Yamauchi and Yoshio Bando and Kumao Uchida and Hiroshi Kitagawa",

year = "2005",

language = "English",

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note = "54th SPSJ Annual Meeting 2005 ; Conference date: 25-05-2005 Through 27-05-2005",

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TY - CONF

T1 - Relative humidity-dependences of proton conductiVities of metal nanoparticles protected by rubeanic acid polymer

AU - Fujishima, Musashi

AU - Ikeda, Ryuichi

AU - Kubo, Takashi

AU - Nakasuji, Kazuhiro

AU - Nagao, Yuki

AU - Yamauchi, Miho

AU - Bando, Yoshio

AU - Uchida, Kumao

AU - Kitagawa, Hiroshi

PY - 2005

Y1 - 2005

N2 - The polymer-protected metal nanoparticle, characterized by a uniform particle size, a monodispersity and a large specific surface area with a chemical stability, has attracted much attention because of its potential application in the hydrogen technology. In this study, by use of a rubeanic acid polymer (RAP) with a dibasic acidic character, polymer-protected noble metal nanoparticles (RAP-Pt, RAP-Pd) with 4~15 nm diameters were successfully synthesized. Their proton conductivities at room temperature show relative humidity (RH)-dependences and reach at remarkably high value (>1×10-2Scm-1) at RH = 100 %. The mechanism of this phenomenon will be also described.

AB - The polymer-protected metal nanoparticle, characterized by a uniform particle size, a monodispersity and a large specific surface area with a chemical stability, has attracted much attention because of its potential application in the hydrogen technology. In this study, by use of a rubeanic acid polymer (RAP) with a dibasic acidic character, polymer-protected noble metal nanoparticles (RAP-Pt, RAP-Pd) with 4~15 nm diameters were successfully synthesized. Their proton conductivities at room temperature show relative humidity (RH)-dependences and reach at remarkably high value (>1×10-2Scm-1) at RH = 100 %. The mechanism of this phenomenon will be also described.

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UR - http://www.scopus.com/inward/citedby.url?scp=33645642185&partnerID=8YFLogxK

M3 - Paper

AN - SCOPUS:33645642185

SP - 1716

T2 - 54th SPSJ Annual Meeting 2005

Y2 - 25 May 2005 through 27 May 2005

ER -

Relative humidity-dependences of proton conductiVities of metal nanoparticles protected by rubeanic acid polymer

Abstract

Other

All Science Journal Classification (ASJC) codes

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