TY - JOUR
T1 - Relationship between molecular structures of uniquely designed
T2 - C 2-symmetric axially chiral dopants and their helical twisting properties in cholesteric liquid crystals
AU - Yoshizawa, Daisuke
AU - Higuchi, Hiroki
AU - Okumura, Yasushi
AU - Kikuchi, Hirotsugu
N1 - Funding Information:
This work was partially supported by a Grant-in-Aid for Scientific Research (A) JSPS KAKENHI Grant Number JP25248021 and 18H03920 from the Japan Society for the Promotion of Science, Dynamic Alliance for Open Innovation Bridging Human, Environment and Materials (2018G1SE043), the Cooperative Research Program of ‘‘Network Joint Research Center for Materials and Devices’’ and CREST, JST (JPMJCR1424).
Funding Information:
This work was partially supported by a Grant-in-Aid for Scientific Research (A) JSPS KAKENHI Grant Number JP25248021 and 18H03920 from the Japan Society for the Promotion of Science, Dynamic Alliance for Open Innovation Bridging Human, Environment and Materials (2018G1SE043), the Cooperative Research Program of "Network Joint Research Center for Materials and Devices" and CREST, JST (JPMJCR1424).
Publisher Copyright:
© 2019 The Royal Society of Chemistry.
PY - 2019
Y1 - 2019
N2 - The induction of chirality in a liquid crystal (LC) can lead to the development of functional LC materials with enhanced properties. A chiral dopant is known to induce a molecular rearrangement and a subsequent helical twisting in the nematic LC host, affording a cholesteric liquid crystal (CLC). However, the chirality transfer mechanism has not been fully elucidated yet. In this study, we newly synthesized 9,9′-biphenanthrene-type chiral dopants ((S)-2s) following our work on binaphthyl-type chiral dopants with the aim of unveiling the chirality transfer mechanism. The molecular structures of the chiral dopants in the crystal were determined by XRD. Significantly unique Cotton effects were observed in (S)-2s, indicating that (S)-2s adopted a different conformation in solution from the binaphthyl-type chiral dopants. Interestingly, one of the (S)-2s dopants shows positive temperature dependence of helical twisting power (HTP) though most chiral dopants show negative temperature dependence. The effects of mixing chiral dopants having opposite temperature dependence of helical twisting power were also investigated. Finally, a CLC showing temperature independency was obtained by mixing two types of chiral dopants with a reverse trend of temperature dependence in HTP.
AB - The induction of chirality in a liquid crystal (LC) can lead to the development of functional LC materials with enhanced properties. A chiral dopant is known to induce a molecular rearrangement and a subsequent helical twisting in the nematic LC host, affording a cholesteric liquid crystal (CLC). However, the chirality transfer mechanism has not been fully elucidated yet. In this study, we newly synthesized 9,9′-biphenanthrene-type chiral dopants ((S)-2s) following our work on binaphthyl-type chiral dopants with the aim of unveiling the chirality transfer mechanism. The molecular structures of the chiral dopants in the crystal were determined by XRD. Significantly unique Cotton effects were observed in (S)-2s, indicating that (S)-2s adopted a different conformation in solution from the binaphthyl-type chiral dopants. Interestingly, one of the (S)-2s dopants shows positive temperature dependence of helical twisting power (HTP) though most chiral dopants show negative temperature dependence. The effects of mixing chiral dopants having opposite temperature dependence of helical twisting power were also investigated. Finally, a CLC showing temperature independency was obtained by mixing two types of chiral dopants with a reverse trend of temperature dependence in HTP.
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U2 - 10.1039/c8tc05296d
DO - 10.1039/c8tc05296d
M3 - Article
AN - SCOPUS:85062209252
SN - 2050-7534
VL - 7
SP - 2225
EP - 2231
JO - Journal of Materials Chemistry C
JF - Journal of Materials Chemistry C
IS - 8
ER -