Regioselective oxidative liberation of aryl-substituted tripyrrinone metal complexes from N-confused porphyrin

Hiroyuki Furuta; Hiromitsu Maeda; Atsuhiro Osuka

doi:10.1021/ol0168521

Regioselective oxidative liberation of aryl-substituted tripyrrinone metal complexes from N-confused porphyrin

Hiroyuki Furuta, Hiromitsu Maeda, Atsuhiro Osuka

Research output: Contribution to journal › Article › peer-review

67 Citations (Scopus)

Abstract

Chemical equation presented M = H₂, Zn(ii), Ni(II), Pd(II), Pt(II) A Cu(II) complex of the first aryl-substituted tripyrrinone derivative, 14-benzoyl-5,10-diphenyl-1-oxo-tripyrrinato copper(II) (3-Cu) was obtained in the reaction of N-confused tetraphenylporphyrin (NCTPP) and Cu(OAc)₂ in refluxing toluene, and subsequent treatment with acid afforded a free tripyrrolic ligand that could bind a variety of transition metals.

Original language	English
Pages (from-to)	181-184
Number of pages	4
Journal	Organic letters
Volume	4
Issue number	2
DOIs	https://doi.org/10.1021/ol0168521
Publication status	Published - 2002

All Science Journal Classification (ASJC) codes

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry

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10.1021/ol0168521

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title = "Regioselective oxidative liberation of aryl-substituted tripyrrinone metal complexes from N-confused porphyrin",

abstract = "Chemical equation presented M = H2, Zn(ii), Ni(II), Pd(II), Pt(II) A Cu(II) complex of the first aryl-substituted tripyrrinone derivative, 14-benzoyl-5,10-diphenyl-1-oxo-tripyrrinato copper(II) (3-Cu) was obtained in the reaction of N-confused tetraphenylporphyrin (NCTPP) and Cu(OAc)2 in refluxing toluene, and subsequent treatment with acid afforded a free tripyrrolic ligand that could bind a variety of transition metals.",

author = "Hiroyuki Furuta and Hiromitsu Maeda and Atsuhiro Osuka",

year = "2002",

doi = "10.1021/ol0168521",

language = "English",

volume = "4",

pages = "181--184",

journal = "Organic letters",

issn = "1523-7060",

publisher = "American Chemical Society",

number = "2",

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T1 - Regioselective oxidative liberation of aryl-substituted tripyrrinone metal complexes from N-confused porphyrin

AU - Furuta, Hiroyuki

AU - Maeda, Hiromitsu

AU - Osuka, Atsuhiro

PY - 2002

Y1 - 2002

N2 - Chemical equation presented M = H2, Zn(ii), Ni(II), Pd(II), Pt(II) A Cu(II) complex of the first aryl-substituted tripyrrinone derivative, 14-benzoyl-5,10-diphenyl-1-oxo-tripyrrinato copper(II) (3-Cu) was obtained in the reaction of N-confused tetraphenylporphyrin (NCTPP) and Cu(OAc)2 in refluxing toluene, and subsequent treatment with acid afforded a free tripyrrolic ligand that could bind a variety of transition metals.

AB - Chemical equation presented M = H2, Zn(ii), Ni(II), Pd(II), Pt(II) A Cu(II) complex of the first aryl-substituted tripyrrinone derivative, 14-benzoyl-5,10-diphenyl-1-oxo-tripyrrinato copper(II) (3-Cu) was obtained in the reaction of N-confused tetraphenylporphyrin (NCTPP) and Cu(OAc)2 in refluxing toluene, and subsequent treatment with acid afforded a free tripyrrolic ligand that could bind a variety of transition metals.

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DO - 10.1021/ol0168521

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SN - 1523-7060

VL - 4

SP - 181

EP - 184

JO - Organic letters

JF - Organic letters

IS - 2

ER -

Regioselective oxidative liberation of aryl-substituted tripyrrinone metal complexes from N-confused porphyrin

Abstract

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