Redox-switched crown ethers monocrown-biscrown interconversion coupled with redox of a thiol-disulfide couple

Takahide Minami; Seiji Shinkai; Osamu Manabe

doi:10.1016/S0040-4039(00)85787-1

Redox-switched crown ethers monocrown-biscrown interconversion coupled with redox of a thiol-disulfide couple

Takahide Minami, Seiji Shinkai, Osamu Manabe

Research output: Contribution to journal › Article › peer-review

18 Citations (Scopus)

Abstract

To give a redox-switch function to crown ethers, 4′-mercaptomono-benzo-15-crown-5 (CrSH) and its oxidized disulfide form (CrSSCr) were synthesized. The solvent extraction proved that the ion affinity of CrSH is generally greater than that of CrSSCr.

Original language	English
Pages (from-to)	5167-5170
Number of pages	4
Journal	Tetrahedron Letters
Volume	23
Issue number	49
DOIs	https://doi.org/10.1016/S0040-4039(00)85787-1
Publication status	Published - Jan 1 1982
Externally published	Yes

All Science Journal Classification (ASJC) codes

Biochemistry
Drug Discovery
Organic Chemistry

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10.1016/S0040-4039(00)85787-1

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title = "Redox-switched crown ethers monocrown-biscrown interconversion coupled with redox of a thiol-disulfide couple",

abstract = "To give a redox-switch function to crown ethers, 4′-mercaptomono-benzo-15-crown-5 (CrSH) and its oxidized disulfide form (CrSSCr) were synthesized. The solvent extraction proved that the ion affinity of CrSH is generally greater than that of CrSSCr.",

author = "Takahide Minami and Seiji Shinkai and Osamu Manabe",

year = "1982",

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doi = "10.1016/S0040-4039(00)85787-1",

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T1 - Redox-switched crown ethers monocrown-biscrown interconversion coupled with redox of a thiol-disulfide couple

AU - Minami, Takahide

AU - Shinkai, Seiji

AU - Manabe, Osamu

PY - 1982/1/1

Y1 - 1982/1/1

N2 - To give a redox-switch function to crown ethers, 4′-mercaptomono-benzo-15-crown-5 (CrSH) and its oxidized disulfide form (CrSSCr) were synthesized. The solvent extraction proved that the ion affinity of CrSH is generally greater than that of CrSSCr.

AB - To give a redox-switch function to crown ethers, 4′-mercaptomono-benzo-15-crown-5 (CrSH) and its oxidized disulfide form (CrSSCr) were synthesized. The solvent extraction proved that the ion affinity of CrSH is generally greater than that of CrSSCr.

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U2 - 10.1016/S0040-4039(00)85787-1

DO - 10.1016/S0040-4039(00)85787-1

M3 - Article

AN - SCOPUS:0000200861

SN - 0040-4039

VL - 23

SP - 5167

EP - 5170

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 49

ER -

Redox-switched crown ethers monocrown-biscrown interconversion coupled with redox of a thiol-disulfide couple

Abstract

All Science Journal Classification (ASJC) codes

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