Rate enhancement with a bowl-shaped phosphane in the rhodium-catalyzed hydrosilylation of ketones

Osamu Niyomura; Makoto Tokunaga; Yasushi Obora; Tetsuo Iwasawa; Yasushi Tsuji

doi:10.1002/anie.200390331

Rate enhancement with a bowl-shaped phosphane in the rhodium-catalyzed hydrosilylation of ketones

Osamu Niyomura
, Makoto Tokunaga
, Yasushi Obora
, Tetsuo Iwasawa
, Yasushi Tsuji

Research output: Contribution to journal › Article › peer-review

59 Citations (Scopus)

Abstract

Up to 154-fold rate enhancement (see picture) and higher yields are achieved with the bowl-shaped triarylphosphane ligand P(tm-tp)₃ compared with common phosphane ligands in Rh-catalyzed hydrosilylation of ketones. The superior performance of P(tm-tp)₃ over the similar P(tp)₃ is apparently related to the deeper bowl formed by the methyl-bearing terphenyl substituents in the former.

Original language	English
Pages (from-to)	1287-1289
Number of pages	3
Journal	Angewandte Chemie - International Edition
Volume	42
Issue number	11
DOIs	https://doi.org/10.1002/anie.200390331
Publication status	Published - Mar 17 2003
Externally published	Yes

All Science Journal Classification (ASJC) codes

Catalysis
General Chemistry

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10.1002/anie.200390331

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title = "Rate enhancement with a bowl-shaped phosphane in the rhodium-catalyzed hydrosilylation of ketones",

abstract = "Up to 154-fold rate enhancement (see picture) and higher yields are achieved with the bowl-shaped triarylphosphane ligand P(tm-tp)3 compared with common phosphane ligands in Rh-catalyzed hydrosilylation of ketones. The superior performance of P(tm-tp)3 over the similar P(tp)3 is apparently related to the deeper bowl formed by the methyl-bearing terphenyl substituents in the former.",

keywords = "Homogeneous catalysis, Hydrosilylation, Ligand effects, P ligands, Rhodium",

author = "Osamu Niyomura and Makoto Tokunaga and Yasushi Obora and Tetsuo Iwasawa and Yasushi Tsuji",

year = "2003",

month = mar,

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doi = "10.1002/anie.200390331",

language = "English",

volume = "42",

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journal = "Angewandte Chemie - International Edition",

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publisher = "John Wiley and Sons Ltd",

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T1 - Rate enhancement with a bowl-shaped phosphane in the rhodium-catalyzed hydrosilylation of ketones

AU - Niyomura, Osamu

AU - Tokunaga, Makoto

AU - Obora, Yasushi

AU - Iwasawa, Tetsuo

AU - Tsuji, Yasushi

PY - 2003/3/17

Y1 - 2003/3/17

N2 - Up to 154-fold rate enhancement (see picture) and higher yields are achieved with the bowl-shaped triarylphosphane ligand P(tm-tp)3 compared with common phosphane ligands in Rh-catalyzed hydrosilylation of ketones. The superior performance of P(tm-tp)3 over the similar P(tp)3 is apparently related to the deeper bowl formed by the methyl-bearing terphenyl substituents in the former.

AB - Up to 154-fold rate enhancement (see picture) and higher yields are achieved with the bowl-shaped triarylphosphane ligand P(tm-tp)3 compared with common phosphane ligands in Rh-catalyzed hydrosilylation of ketones. The superior performance of P(tm-tp)3 over the similar P(tp)3 is apparently related to the deeper bowl formed by the methyl-bearing terphenyl substituents in the former.

KW - Homogeneous catalysis

KW - Hydrosilylation

KW - Ligand effects

KW - P ligands

KW - Rhodium

UR - https://www.scopus.com/pages/publications/0037451408

UR - https://www.scopus.com/pages/publications/0037451408#tab=citedBy

U2 - 10.1002/anie.200390331

DO - 10.1002/anie.200390331

M3 - Article

C2 - 12645066

AN - SCOPUS:0037451408

SN - 1433-7851

VL - 42

SP - 1287

EP - 1289

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 11

ER -

Rate enhancement with a bowl-shaped phosphane in the rhodium-catalyzed hydrosilylation of ketones

Abstract

All Science Journal Classification (ASJC) codes

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