Pt(II) N-confused porphyrin: An expanded pyrrole that affords a stable π-anion

Dong Hoon Won; Motoki Toganoh; Hidemitsu Uno; Hiroyuki Furuta

doi:10.1039/b906018a

Pt(II) N-confused porphyrin: An expanded pyrrole that affords a stable π-anion

Dong Hoon Won, Motoki Toganoh, Hidemitsu Uno, Hiroyuki Furuta

Research output: Contribution to journal › Article › peer-review

31 Citations (Scopus)

Abstract

Pt(II) complex of meso-tetrakis(pentafluorophenyl) N-confused porphyrin (1-Pt) efficiently binds Cl^-, Br^-, and I^- anions at the peripheral N-H, while deprotonation proceeds with F^-, H₂PO₄^-, and OH^- in CH ₂Cl₂ solution; neutral and anionic structures of 1-Pt were characterized by single crystal X-ray diffraction analysis.

Original language	English
Pages (from-to)	6151-6158
Number of pages	8
Journal	Dalton Transactions
Issue number	31
DOIs	https://doi.org/10.1039/b906018a
Publication status	Published - 2009

All Science Journal Classification (ASJC) codes

Inorganic Chemistry

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10.1039/b906018a

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abstract = "Pt(II) complex of meso-tetrakis(pentafluorophenyl) N-confused porphyrin (1-Pt) efficiently binds Cl-, Br-, and I- anions at the peripheral N-H, while deprotonation proceeds with F-, H2PO4-, and OH- in CH 2Cl2 solution; neutral and anionic structures of 1-Pt were characterized by single crystal X-ray diffraction analysis.",

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AU - Toganoh, Motoki

AU - Uno, Hidemitsu

AU - Furuta, Hiroyuki

PY - 2009

Y1 - 2009

N2 - Pt(II) complex of meso-tetrakis(pentafluorophenyl) N-confused porphyrin (1-Pt) efficiently binds Cl-, Br-, and I- anions at the peripheral N-H, while deprotonation proceeds with F-, H2PO4-, and OH- in CH 2Cl2 solution; neutral and anionic structures of 1-Pt were characterized by single crystal X-ray diffraction analysis.

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ER -

Pt(II) N-confused porphyrin: An expanded pyrrole that affords a stable π-anion

Abstract

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