Protonic-electronic mixed conduction and hydrogen permeation in BaCe 0.9-xY0.1RuxO3-α

Hiroshige Matsumoto; Tetsuo Shimura; Tohru Higuchi; Hiroomi Tanaka; Koji Katahira; Takanori Otake; Takao Kudo; Keyi Yashiro; Atsushi Kaimai; Tatsuya Kawada; Junichiro Mizusaki

doi:10.1149/1.1852442

Protonic-electronic mixed conduction and hydrogen permeation in BaCe _0.9-xY_0.1Ru_xO_3-α

Hiroshige Matsumoto, Tetsuo Shimura, Tohru Higuchi, Hiroomi Tanaka, Koji Katahira, Takanori Otake, Takao Kudo, Keyi Yashiro, Atsushi Kaimai, Tatsuya Kawada, Junichiro Mizusaki

Advanced Energy Conversion Systems Thrust

Research output: Contribution to journal › Article › peer-review

65 Citations (Scopus)

Abstract

The protonic-electronic mixed conductors are of great interest for their potential applications particularly for the hydrogen separation that is essential for hydrogen production from hydrocarbons. This paper deals with the mixed conduction properties of BaCe_0.9-xY_0.1Ru _xO_3-a (x = 0-0.1) in which Ru is partially substituted for Ce in the high-temperature proton conductor, BaCe_0.9Y _0.1O_3-α. Appreciable hydrogen permeation through the Ru-doped materials was observed and is attributed to ambipolar diffusion. The mixed conducting mechanism is discussed in terms of the defect chemistry and electronic structures revealed by the electrochemical and spectroscopic measurements. (c) 2005 The Electrochemical Society. All rights reserved.

Original language	English
Pages (from-to)	A488-A492
Journal	Journal of the Electrochemical Society
Volume	152
Issue number	3
DOIs	https://doi.org/10.1149/1.1852442
Publication status	Published - 2005

All Science Journal Classification (ASJC) codes

Electronic, Optical and Magnetic Materials
Renewable Energy, Sustainability and the Environment
Surfaces, Coatings and Films
Electrochemistry
Materials Chemistry

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

Access to Document

10.1149/1.1852442

Cite this

@article{64cc301dceeb41ed81ca5a80ac814a5b,

title = "Protonic-electronic mixed conduction and hydrogen permeation in BaCe 0.9-xY0.1RuxO3-α",

abstract = "The protonic-electronic mixed conductors are of great interest for their potential applications particularly for the hydrogen separation that is essential for hydrogen production from hydrocarbons. This paper deals with the mixed conduction properties of BaCe0.9-xY0.1Ru xO3-a (x = 0-0.1) in which Ru is partially substituted for Ce in the high-temperature proton conductor, BaCe0.9Y 0.1O3-α. Appreciable hydrogen permeation through the Ru-doped materials was observed and is attributed to ambipolar diffusion. The mixed conducting mechanism is discussed in terms of the defect chemistry and electronic structures revealed by the electrochemical and spectroscopic measurements. (c) 2005 The Electrochemical Society. All rights reserved.",

author = "Hiroshige Matsumoto and Tetsuo Shimura and Tohru Higuchi and Hiroomi Tanaka and Koji Katahira and Takanori Otake and Takao Kudo and Keyi Yashiro and Atsushi Kaimai and Tatsuya Kawada and Junichiro Mizusaki",

year = "2005",

doi = "10.1149/1.1852442",

language = "English",

volume = "152",

pages = "A488--A492",

journal = "Journal of the Electrochemical Society",

issn = "0013-4651",

publisher = "Electrochemical Society, Inc.",

number = "3",

}

TY - JOUR

T1 - Protonic-electronic mixed conduction and hydrogen permeation in BaCe 0.9-xY0.1RuxO3-α

AU - Matsumoto, Hiroshige

AU - Shimura, Tetsuo

AU - Higuchi, Tohru

AU - Tanaka, Hiroomi

AU - Katahira, Koji

AU - Otake, Takanori

AU - Kudo, Takao

AU - Yashiro, Keyi

AU - Kaimai, Atsushi

AU - Kawada, Tatsuya

AU - Mizusaki, Junichiro

PY - 2005

Y1 - 2005

N2 - The protonic-electronic mixed conductors are of great interest for their potential applications particularly for the hydrogen separation that is essential for hydrogen production from hydrocarbons. This paper deals with the mixed conduction properties of BaCe0.9-xY0.1Ru xO3-a (x = 0-0.1) in which Ru is partially substituted for Ce in the high-temperature proton conductor, BaCe0.9Y 0.1O3-α. Appreciable hydrogen permeation through the Ru-doped materials was observed and is attributed to ambipolar diffusion. The mixed conducting mechanism is discussed in terms of the defect chemistry and electronic structures revealed by the electrochemical and spectroscopic measurements. (c) 2005 The Electrochemical Society. All rights reserved.

AB - The protonic-electronic mixed conductors are of great interest for their potential applications particularly for the hydrogen separation that is essential for hydrogen production from hydrocarbons. This paper deals with the mixed conduction properties of BaCe0.9-xY0.1Ru xO3-a (x = 0-0.1) in which Ru is partially substituted for Ce in the high-temperature proton conductor, BaCe0.9Y 0.1O3-α. Appreciable hydrogen permeation through the Ru-doped materials was observed and is attributed to ambipolar diffusion. The mixed conducting mechanism is discussed in terms of the defect chemistry and electronic structures revealed by the electrochemical and spectroscopic measurements. (c) 2005 The Electrochemical Society. All rights reserved.

UR - http://www.scopus.com/inward/record.url?scp=20144382214&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=20144382214&partnerID=8YFLogxK

U2 - 10.1149/1.1852442

DO - 10.1149/1.1852442

M3 - Article

AN - SCOPUS:20144382214

SN - 0013-4651

VL - 152

SP - A488-A492

JO - Journal of the Electrochemical Society

JF - Journal of the Electrochemical Society

IS - 3

ER -