Protection and deprotection approach for the introduction of functional groups into metal-organic frameworks

Teppei Yamada; Hiroshi Kitagawa

doi:10.1021/ja809352y

Protection and deprotection approach for the introduction of functional groups into metal-organic frameworks

Teppei Yamada, Hiroshi Kitagawa

Applied Chemistry

Research output: Contribution to journal › Article › peer-review

124 Citations (Scopus)

Abstract

A noncoordinating hydroxyl group was introduced into a metal-organic framework (MOF) by a procedure involving a protection, complexation, and deprotection (PCD) reaction sequence, and the crystal structure of a novel MOF, [Zn(dhybdc)(bpy)]64DMF (1), was determined. 1 did not have an interpenetrated structure. The three-dimensional pores had arge apertures. Results showed that the PCD method is a novel synthetic method for the introduction of various functional groups into MOFs.

Original language	English
Pages (from-to)	6312-6313
Number of pages	2
Journal	Journal of the American Chemical Society
Volume	131
Issue number	18
DOIs	https://doi.org/10.1021/ja809352y
Publication status	Published - May 13 2009

All Science Journal Classification (ASJC) codes

Chemistry(all)
Catalysis
Biochemistry
Colloid and Surface Chemistry

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10.1021/ja809352y

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abstract = "A noncoordinating hydroxyl group was introduced into a metal-organic framework (MOF) by a procedure involving a protection, complexation, and deprotection (PCD) reaction sequence, and the crystal structure of a novel MOF, [Zn(dhybdc)(bpy)]64DMF (1), was determined. 1 did not have an interpenetrated structure. The three-dimensional pores had arge apertures. Results showed that the PCD method is a novel synthetic method for the introduction of various functional groups into MOFs.",

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AB - A noncoordinating hydroxyl group was introduced into a metal-organic framework (MOF) by a procedure involving a protection, complexation, and deprotection (PCD) reaction sequence, and the crystal structure of a novel MOF, [Zn(dhybdc)(bpy)]64DMF (1), was determined. 1 did not have an interpenetrated structure. The three-dimensional pores had arge apertures. Results showed that the PCD method is a novel synthetic method for the introduction of various functional groups into MOFs.

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Protection and deprotection approach for the introduction of functional groups into metal-organic frameworks

Abstract

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