Programmed formation of nanogels via a radical crossover reaction of complementarily reactive diblock copolymers

Yoshifumi Amamoto; Yuji Higaki; Yasuhiro Matsuda; Hideyuki Otsuka; Atsushi Takahara

doi:10.1246/cl.2007.774

Programmed formation of nanogels via a radical crossover reaction of complementarily reactive diblock copolymers

Yoshifumi Amamoto, Yuji Higaki, Yasuhiro Matsuda, Hideyuki Otsuka, Atsushi Takahara

Department of Applied Molecular Chemistry

Research output: Contribution to journal › Article › peer-review

24 Citations (Scopus)

Abstract

By heating two types of diblock copolymers with complementarity reactive alkoxyamine units in the side chains, nanogels were formed as a result of a radical crossover reaction of the alkoxyamine units. The transformation from the diblock copolymers to nanogels and their absolute molecular weight were obviously dependent on reaction concentrations and the mixing ratio of two types of diblock copolymers.

Original language	English
Pages (from-to)	774-775
Number of pages	2
Journal	Chemistry Letters
Volume	36
Issue number	6
DOIs	https://doi.org/10.1246/cl.2007.774
Publication status	Published - Jun 5 2007

All Science Journal Classification (ASJC) codes

Chemistry(all)

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10.1246/cl.2007.774

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abstract = "By heating two types of diblock copolymers with complementarity reactive alkoxyamine units in the side chains, nanogels were formed as a result of a radical crossover reaction of the alkoxyamine units. The transformation from the diblock copolymers to nanogels and their absolute molecular weight were obviously dependent on reaction concentrations and the mixing ratio of two types of diblock copolymers.",

author = "Yoshifumi Amamoto and Yuji Higaki and Yasuhiro Matsuda and Hideyuki Otsuka and Atsushi Takahara",

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AU - Otsuka, Hideyuki

AU - Takahara, Atsushi

PY - 2007/6/5

Y1 - 2007/6/5

N2 - By heating two types of diblock copolymers with complementarity reactive alkoxyamine units in the side chains, nanogels were formed as a result of a radical crossover reaction of the alkoxyamine units. The transformation from the diblock copolymers to nanogels and their absolute molecular weight were obviously dependent on reaction concentrations and the mixing ratio of two types of diblock copolymers.

AB - By heating two types of diblock copolymers with complementarity reactive alkoxyamine units in the side chains, nanogels were formed as a result of a radical crossover reaction of the alkoxyamine units. The transformation from the diblock copolymers to nanogels and their absolute molecular weight were obviously dependent on reaction concentrations and the mixing ratio of two types of diblock copolymers.

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Programmed formation of nanogels via a radical crossover reaction of complementarily reactive diblock copolymers

Abstract

All Science Journal Classification (ASJC) codes

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