Programmed asymmetrical trimer formation of β-alkyl N-confused porphyrin zinc(II) complex

Motoki Toganoh; Hiroaki Ogawa; Tatsuki Morimoto; Hiroyuki Furuta

doi:10.1080/10610270802588293

Programmed asymmetrical trimer formation of β-alkyl N-confused porphyrin zinc(II) complex

Motoki Toganoh, Hiroaki Ogawa, Tatsuki Morimoto, Hiroyuki Furuta

Research output: Contribution to journal › Article › peer-review

9 Citations (Scopus)

Abstract

Self-coordination of β-alkyl N-confused porphyrin (NCP) zinc(II) complexes has been studied to reveal that asymmetrical trimers formed exclusively. A key factor to control the configuration of the trimers (symmetric or asymmetric) has been studied theoretically, and revealed that the steric environment around the peripheral nitrogen atoms as well as rotational angles of the confused pyrrole rings play a crucial role in trimer formation of β-alkyl NCP zinc(II) complexes.

Original language	English
Pages (from-to)	324-330
Number of pages	7
Journal	Supramolecular Chemistry
Volume	21
Issue number	3-4
DOIs	https://doi.org/10.1080/10610270802588293
Publication status	Published - 2009

All Science Journal Classification (ASJC) codes

Chemistry(all)

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10.1080/10610270802588293

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title = "Programmed asymmetrical trimer formation of β-alkyl N-confused porphyrin zinc(II) complex",

abstract = "Self-coordination of β-alkyl N-confused porphyrin (NCP) zinc(II) complexes has been studied to reveal that asymmetrical trimers formed exclusively. A key factor to control the configuration of the trimers (symmetric or asymmetric) has been studied theoretically, and revealed that the steric environment around the peripheral nitrogen atoms as well as rotational angles of the confused pyrrole rings play a crucial role in trimer formation of β-alkyl NCP zinc(II) complexes.",

author = "Motoki Toganoh and Hiroaki Ogawa and Tatsuki Morimoto and Hiroyuki Furuta",

note = "Funding Information: The present work was supported by the Global COE Program {\textquoteleft}Science for Future Molecular Systems{\textquoteright} from the Ministry of Education, Culture, Sports, Science and Technology of Japan.",

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T1 - Programmed asymmetrical trimer formation of β-alkyl N-confused porphyrin zinc(II) complex

AU - Toganoh, Motoki

AU - Ogawa, Hiroaki

AU - Morimoto, Tatsuki

AU - Furuta, Hiroyuki

N1 - Funding Information: The present work was supported by the Global COE Program ‘Science for Future Molecular Systems’ from the Ministry of Education, Culture, Sports, Science and Technology of Japan.

PY - 2009

Y1 - 2009

N2 - Self-coordination of β-alkyl N-confused porphyrin (NCP) zinc(II) complexes has been studied to reveal that asymmetrical trimers formed exclusively. A key factor to control the configuration of the trimers (symmetric or asymmetric) has been studied theoretically, and revealed that the steric environment around the peripheral nitrogen atoms as well as rotational angles of the confused pyrrole rings play a crucial role in trimer formation of β-alkyl NCP zinc(II) complexes.

AB - Self-coordination of β-alkyl N-confused porphyrin (NCP) zinc(II) complexes has been studied to reveal that asymmetrical trimers formed exclusively. A key factor to control the configuration of the trimers (symmetric or asymmetric) has been studied theoretically, and revealed that the steric environment around the peripheral nitrogen atoms as well as rotational angles of the confused pyrrole rings play a crucial role in trimer formation of β-alkyl NCP zinc(II) complexes.

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Programmed asymmetrical trimer formation of β-alkyl N-confused porphyrin zinc(II) complex

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