Preparation of TiO2 hollow-fibers using supramolecular assemblies

Satoshi Kobayashi; Kenji Hanabusa; Nobuhiro Hamasaki; Mutsumi Kimura; Hirofusa Shirai; Seiji Shinkai

doi:10.1021/cm0000907

Preparation of TiO₂ hollow-fibers using supramolecular assemblies

Satoshi Kobayashi, Kenji Hanabusa, Nobuhiro Hamasaki, Mutsumi Kimura, Hirofusa Shirai, Seiji Shinkai

Research output: Contribution to journal › Article › peer-review

267 Citations (Scopus)

Abstract

trans-(1R,2R)-1,2-Cyclohexanedi(11-aminocarbonylundecylpyridinium) hexafluorophosphate (1) was synthesized. The sol-gel polymerization of Ti[OCH(CH₃)₂]₄ using compound 1 as a self-assembled template afforded fibrous TiO₂ materials with a 'macaroni'-like structure. The unique structure of TiO₂ could be created by the formation of a fibrous self-assembled aggregate and electrostatic interaction between anionic titania species and cationic 1 under basic conditions.

Original language	English
Pages (from-to)	1523-1525
Number of pages	3
Journal	Chemistry of Materials
Volume	12
Issue number	6
DOIs	https://doi.org/10.1021/cm0000907
Publication status	Published - Jun 2000
Externally published	Yes

All Science Journal Classification (ASJC) codes

Chemistry(all)
Chemical Engineering(all)
Materials Chemistry

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10.1021/cm0000907

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title = "Preparation of TiO2 hollow-fibers using supramolecular assemblies",

abstract = "trans-(1R,2R)-1,2-Cyclohexanedi(11-aminocarbonylundecylpyridinium) hexafluorophosphate (1) was synthesized. The sol-gel polymerization of Ti[OCH(CH3)2]4 using compound 1 as a self-assembled template afforded fibrous TiO2 materials with a 'macaroni'-like structure. The unique structure of TiO2 could be created by the formation of a fibrous self-assembled aggregate and electrostatic interaction between anionic titania species and cationic 1 under basic conditions.",

author = "Satoshi Kobayashi and Kenji Hanabusa and Nobuhiro Hamasaki and Mutsumi Kimura and Hirofusa Shirai and Seiji Shinkai",

year = "2000",

month = jun,

doi = "10.1021/cm0000907",

language = "English",

volume = "12",

pages = "1523--1525",

journal = "Chemistry of Materials",

issn = "0897-4756",

publisher = "American Chemical Society",

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T1 - Preparation of TiO2 hollow-fibers using supramolecular assemblies

AU - Kobayashi, Satoshi

AU - Hanabusa, Kenji

AU - Hamasaki, Nobuhiro

AU - Kimura, Mutsumi

AU - Shirai, Hirofusa

AU - Shinkai, Seiji

PY - 2000/6

Y1 - 2000/6

N2 - trans-(1R,2R)-1,2-Cyclohexanedi(11-aminocarbonylundecylpyridinium) hexafluorophosphate (1) was synthesized. The sol-gel polymerization of Ti[OCH(CH3)2]4 using compound 1 as a self-assembled template afforded fibrous TiO2 materials with a 'macaroni'-like structure. The unique structure of TiO2 could be created by the formation of a fibrous self-assembled aggregate and electrostatic interaction between anionic titania species and cationic 1 under basic conditions.

AB - trans-(1R,2R)-1,2-Cyclohexanedi(11-aminocarbonylundecylpyridinium) hexafluorophosphate (1) was synthesized. The sol-gel polymerization of Ti[OCH(CH3)2]4 using compound 1 as a self-assembled template afforded fibrous TiO2 materials with a 'macaroni'-like structure. The unique structure of TiO2 could be created by the formation of a fibrous self-assembled aggregate and electrostatic interaction between anionic titania species and cationic 1 under basic conditions.

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M3 - Article

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EP - 1525

JO - Chemistry of Materials

JF - Chemistry of Materials

IS - 6

ER -

Preparation of TiO₂ hollow-fibers using supramolecular assemblies

Abstract

All Science Journal Classification (ASJC) codes

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