Preparation of Self-Supporting Ultrathin Films of Titania by Spin Coating

Mineo Hashizume, Toyoki Kunitake

Research output: Contribution to journalArticlepeer-review

54 Citations (Scopus)


A spin-coating process was developed for the preparation of self-supporting ultrathin films of titania. First, an ultrathin layer of poly(vinyl alcohol) (PVA) was formed by spin coating on the surface of an ethanol-soluble polymer that had been preformed on the surface of a Si wafer as a polymer underlayer. Titanium tetrabutoxide [Ti(OnBu)4] in chloroform was then spin-coated onto the PVA layer. The polymer underlayer was dissolved in ethanol, and a self-supporting ultrathin PVA/titania composite film was finally detached from the substrate. Precursor mixtures of Ti(O nBu)4 and small organic molecules were similarly used to obtain self-supporting ultrathin PVA/(organic compounds + titania) composite films. The organic molecules could be removed from the ultrathin film under mild conditions such as aqueous ammonia extraction and low-temperature oxygen plasma treatment. Nanopores were formed by the O2 plasma treatment, as evidenced by transmission electron microscopy. When (4-phenylazo)benzoic acid was used as a small-molecule component, the resulting film contained nanopores that selectively bound the template molecule. It is remarkable that a titania film with thickness of only 10 - 20 nm can be macroscopically uniform and self-supporting. The imprinted nanopore should be useful for development of permselective ceramic membranes.

Original languageEnglish
Pages (from-to)10172-10178
Number of pages7
Issue number24
Publication statusPublished - Nov 25 2003
Externally publishedYes

All Science Journal Classification (ASJC) codes

  • Condensed Matter Physics
  • Spectroscopy
  • General Materials Science
  • Surfaces and Interfaces
  • Electrochemistry


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