Preparation of N-grafted polyanilines utilizing ring-opening copolymerization of epoxide: Tuning of solubility and optical and electrochemical properties of polyaniline

Takuma Yasuda; Isao Yamaguchi; Takakazu Yamamoto

doi:10.1016/S0379-6779(03)00080-8

Preparation of N-grafted polyanilines utilizing ring-opening copolymerization of epoxide: Tuning of solubility and optical and electrochemical properties of polyaniline

Takuma Yasuda, Isao Yamaguchi, Takakazu Yamamoto

Research output: Contribution to journal › Article › peer-review

7 Citations (Scopus)

Abstract

Polyanilines with various degrees of N-grafting have been synthesized by using ring-opening copolymerization of glycidyl phenyl ether (1,2-epoxy-3-phenoxypropane). The obtained polymer has good solubility in common organic solvents. Optical and thermal properties of the N-grafted polyanilines varying with the degree of the N-grafting and length of the graft side chain have been revealed. The polymer received electrochemical oxidation at about 0.40V versus Ag⁺/Ag in a CH₃CN solution of 0.10M LiBF₄.

Original language	English
Pages (from-to)	35-38
Number of pages	4
Journal	Synthetic Metals
Volume	139
Issue number	1
DOIs	https://doi.org/10.1016/S0379-6779(03)00080-8
Publication status	Published - Aug 8 2003
Externally published	Yes

All Science Journal Classification (ASJC) codes

Electronic, Optical and Magnetic Materials
Condensed Matter Physics
Mechanics of Materials
Mechanical Engineering
Metals and Alloys
Materials Chemistry

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10.1016/S0379-6779(03)00080-8

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title = "Preparation of N-grafted polyanilines utilizing ring-opening copolymerization of epoxide: Tuning of solubility and optical and electrochemical properties of polyaniline",

abstract = "Polyanilines with various degrees of N-grafting have been synthesized by using ring-opening copolymerization of glycidyl phenyl ether (1,2-epoxy-3-phenoxypropane). The obtained polymer has good solubility in common organic solvents. Optical and thermal properties of the N-grafted polyanilines varying with the degree of the N-grafting and length of the graft side chain have been revealed. The polymer received electrochemical oxidation at about 0.40V versus Ag+/Ag in a CH3CN solution of 0.10M LiBF4.",

author = "Takuma Yasuda and Isao Yamaguchi and Takakazu Yamamoto",

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T1 - Preparation of N-grafted polyanilines utilizing ring-opening copolymerization of epoxide

T2 - Tuning of solubility and optical and electrochemical properties of polyaniline

AU - Yasuda, Takuma

AU - Yamaguchi, Isao

AU - Yamamoto, Takakazu

PY - 2003/8/8

Y1 - 2003/8/8

N2 - Polyanilines with various degrees of N-grafting have been synthesized by using ring-opening copolymerization of glycidyl phenyl ether (1,2-epoxy-3-phenoxypropane). The obtained polymer has good solubility in common organic solvents. Optical and thermal properties of the N-grafted polyanilines varying with the degree of the N-grafting and length of the graft side chain have been revealed. The polymer received electrochemical oxidation at about 0.40V versus Ag+/Ag in a CH3CN solution of 0.10M LiBF4.

AB - Polyanilines with various degrees of N-grafting have been synthesized by using ring-opening copolymerization of glycidyl phenyl ether (1,2-epoxy-3-phenoxypropane). The obtained polymer has good solubility in common organic solvents. Optical and thermal properties of the N-grafted polyanilines varying with the degree of the N-grafting and length of the graft side chain have been revealed. The polymer received electrochemical oxidation at about 0.40V versus Ag+/Ag in a CH3CN solution of 0.10M LiBF4.

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Preparation of N-grafted polyanilines utilizing ring-opening copolymerization of epoxide: Tuning of solubility and optical and electrochemical properties of polyaniline

Abstract

All Science Journal Classification (ASJC) codes

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