TY - JOUR
T1 - Preparation and reactivity of a nickel dihydride complex
AU - Matsumoto, Takahiro
AU - Nagahama, Takuma
AU - Cho, Jaeheung
AU - Hizume, Takuhiro
AU - Suzuki, Masatatsu
AU - Ogo, Seiji
PY - 2011/11/4
Y1 - 2011/11/4
N2 - A generous donor: A dinuclear octahedral bis(μ-hydrido)dinickel(II) complex (see picture; C gray, H black, N blue, Ni green) acts as an electron donor to reduce electron acceptors such as methyl viologen. The complex is proposed as a functional model for the dihydride intermediate of an NiRu hydrogenase mimic and, by extension, of [NiFe]hydrogenase itself.
AB - A generous donor: A dinuclear octahedral bis(μ-hydrido)dinickel(II) complex (see picture; C gray, H black, N blue, Ni green) acts as an electron donor to reduce electron acceptors such as methyl viologen. The complex is proposed as a functional model for the dihydride intermediate of an NiRu hydrogenase mimic and, by extension, of [NiFe]hydrogenase itself.
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U2 - 10.1002/anie.201104918
DO - 10.1002/anie.201104918
M3 - Article
C2 - 21919169
AN - SCOPUS:80155214281
SN - 1433-7851
VL - 50
SP - 10578
EP - 10580
JO - Angewandte Chemie - International Edition
JF - Angewandte Chemie - International Edition
IS - 45
ER -