Potassium fluoride-induced 1,4-elimination of o-[(trimethylsilyl)methyl] benzyl acetates: A versatile generation of o-quinodimethanes

Ryoichi Kuwano; Takenori Shige

doi:10.1246/cl.2005.728

Potassium fluoride-induced 1,4-elimination of o-[(trimethylsilyl)methyl] benzyl acetates: A versatile generation of o-quinodimethanes

Ryoichi Kuwano, Takenori Shige

Multidisciplinary chemistry

Research output: Contribution to journal › Article › peer-review

13 Citations (Scopus)

Abstract

o-Quinodimethane interemediate was generated from o-[(trimethylsilyl) methyl]benzyl acetate with potassium fluoride. The o-quinodimethane in hand reacted with electron-deficient olefins, affording [4+2] cycloadducts, tetrahydronaphthalenes.

Original language	English
Pages (from-to)	728-729
Number of pages	2
Journal	Chemistry Letters
Volume	34
Issue number	5
DOIs	https://doi.org/10.1246/cl.2005.728
Publication status	Published - May 5 2005

All Science Journal Classification (ASJC) codes

Chemistry(all)

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10.1246/cl.2005.728

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abstract = "o-Quinodimethane interemediate was generated from o-[(trimethylsilyl) methyl]benzyl acetate with potassium fluoride. The o-quinodimethane in hand reacted with electron-deficient olefins, affording [4+2] cycloadducts, tetrahydronaphthalenes.",

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AB - o-Quinodimethane interemediate was generated from o-[(trimethylsilyl) methyl]benzyl acetate with potassium fluoride. The o-quinodimethane in hand reacted with electron-deficient olefins, affording [4+2] cycloadducts, tetrahydronaphthalenes.

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Potassium fluoride-induced 1,4-elimination of o-[(trimethylsilyl)methyl] benzyl acetates: A versatile generation of o-quinodimethanes

Abstract

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