Post-synthetic Modification of a Dinuclear Spin Crossover Iron(III) Complex

Yuki Komatsumaru; Manabu Nakaya; Fumiya Kobayashi; Ryo Ohtani; Masaaki Nakamura; Leonard F. Lindoy; Shinya Hayami

doi:10.1002/zaac.201800087

Post-synthetic Modification of a Dinuclear Spin Crossover Iron(III) Complex

Yuki Komatsumaru, Manabu Nakaya, Fumiya Kobayashi, Ryo Ohtani, Masaaki Nakamura, Leonard F. Lindoy, Shinya Hayami

Research output: Contribution to journal › Article › peer-review

9 Citations (Scopus)

Abstract

The dinuclear iron(III) complex [Fe(salten)₂(bipytz)](BPh₄)₂·EtOH (1) was synthesized and its post-synthesis modification yielded [Fe(salten)₂(bipydz)](BPh₄)₂·EtOH (2). The crystal structures and magnetic behaviors of 1 and 2 were investigated by variable temperature XRD, magnetic susceptibility, and Mössbauer spectra measurements, with each of these dinuclear iron(III) complexes exhibiting gradual spin crossover behavior.

Original language	English
Pages (from-to)	729-734
Number of pages	6
Journal	Zeitschrift fur Anorganische und Allgemeine Chemie
Volume	644
Issue number	14
DOIs	https://doi.org/10.1002/zaac.201800087
Publication status	Published - Aug 2 2018
Externally published	Yes

All Science Journal Classification (ASJC) codes

Inorganic Chemistry

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title = "Post-synthetic Modification of a Dinuclear Spin Crossover Iron(III) Complex",

abstract = "The dinuclear iron(III) complex [Fe(salten)2(bipytz)](BPh4)2·EtOH (1) was synthesized and its post-synthesis modification yielded [Fe(salten)2(bipydz)](BPh4)2·EtOH (2). The crystal structures and magnetic behaviors of 1 and 2 were investigated by variable temperature XRD, magnetic susceptibility, and M{\"o}ssbauer spectra measurements, with each of these dinuclear iron(III) complexes exhibiting gradual spin crossover behavior.",

author = "Yuki Komatsumaru and Manabu Nakaya and Fumiya Kobayashi and Ryo Ohtani and Masaaki Nakamura and Lindoy, {Leonard F.} and Shinya Hayami",

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T1 - Post-synthetic Modification of a Dinuclear Spin Crossover Iron(III) Complex

AU - Komatsumaru, Yuki

AU - Nakaya, Manabu

AU - Kobayashi, Fumiya

AU - Ohtani, Ryo

AU - Nakamura, Masaaki

AU - Lindoy, Leonard F.

AU - Hayami, Shinya

PY - 2018/8/2

Y1 - 2018/8/2

N2 - The dinuclear iron(III) complex [Fe(salten)2(bipytz)](BPh4)2·EtOH (1) was synthesized and its post-synthesis modification yielded [Fe(salten)2(bipydz)](BPh4)2·EtOH (2). The crystal structures and magnetic behaviors of 1 and 2 were investigated by variable temperature XRD, magnetic susceptibility, and Mössbauer spectra measurements, with each of these dinuclear iron(III) complexes exhibiting gradual spin crossover behavior.

AB - The dinuclear iron(III) complex [Fe(salten)2(bipytz)](BPh4)2·EtOH (1) was synthesized and its post-synthesis modification yielded [Fe(salten)2(bipydz)](BPh4)2·EtOH (2). The crystal structures and magnetic behaviors of 1 and 2 were investigated by variable temperature XRD, magnetic susceptibility, and Mössbauer spectra measurements, with each of these dinuclear iron(III) complexes exhibiting gradual spin crossover behavior.

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Post-synthetic Modification of a Dinuclear Spin Crossover Iron(III) Complex

Abstract

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